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Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]

The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa­hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms fr...

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Detalles Bibliográficos
Autores principales: Wu, Longfei, Huang, Linxia, Shu, Mouhai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343826/
https://www.ncbi.nlm.nih.gov/pubmed/22589800
http://dx.doi.org/10.1107/S1600536812010355
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author Wu, Longfei
Huang, Linxia
Shu, Mouhai
author_facet Wu, Longfei
Huang, Linxia
Shu, Mouhai
author_sort Wu, Longfei
collection PubMed
description The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa­hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water mol­ecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxide anions resulting in a Cu(2)O(2) loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H⋯O hydrogen bonds between the coodinated water mol­ecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Inter­molecular π–π inter­actions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å.
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spelling pubmed-33438262012-05-15 Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] Wu, Longfei Huang, Linxia Shu, Mouhai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octa­hedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water mol­ecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxide anions resulting in a Cu(2)O(2) loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H⋯O hydrogen bonds between the coodinated water mol­ecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Inter­molecular π–π inter­actions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343826/ /pubmed/22589800 http://dx.doi.org/10.1107/S1600536812010355 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Longfei
Huang, Linxia
Shu, Mouhai
Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title_full Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title_fullStr Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title_full_unstemmed Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title_short Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis­[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
title_sort poly[diaquadi-μ-hydroxido-κ(4) o:o-dinitrato-κ(4) o:o′-bis­[3-(pyridin-4-yl-κn)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343826/
https://www.ncbi.nlm.nih.gov/pubmed/22589800
http://dx.doi.org/10.1107/S1600536812010355
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