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Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]
The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octahedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms fr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343826/ https://www.ncbi.nlm.nih.gov/pubmed/22589800 http://dx.doi.org/10.1107/S1600536812010355 |
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author | Wu, Longfei Huang, Linxia Shu, Mouhai |
author_facet | Wu, Longfei Huang, Linxia Shu, Mouhai |
author_sort | Wu, Longfei |
collection | PubMed |
description | The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octahedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water molecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxide anions resulting in a Cu(2)O(2) loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H⋯O hydrogen bonds between the coodinated water molecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Intermolecular π–π interactions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å. |
format | Online Article Text |
id | pubmed-3343826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438262012-05-15 Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] Wu, Longfei Huang, Linxia Shu, Mouhai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(NO(3))(2)(OH)(2)(C(12)H(8)N(4)O)(2)(H(2)O)(2)](n), consists of a neutral polymeric Cu(II) complex in which each Cu(II) atom has a distorted octahedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water molecule, two nitrates and two hydroxides. Two Cu(II) ions are bridged by two hydroxide anions resulting in a Cu(2)O(2) loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H⋯O hydrogen bonds between the coodinated water molecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Intermolecular π–π interactions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343826/ /pubmed/22589800 http://dx.doi.org/10.1107/S1600536812010355 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Longfei Huang, Linxia Shu, Mouhai Poly[diaquadi-μ-hydroxido-κ(4) O:O-dinitrato-κ(4) O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title | Poly[diaquadi-μ-hydroxido-κ(4)
O:O-dinitrato-κ(4)
O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title_full | Poly[diaquadi-μ-hydroxido-κ(4)
O:O-dinitrato-κ(4)
O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title_fullStr | Poly[diaquadi-μ-hydroxido-κ(4)
O:O-dinitrato-κ(4)
O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title_full_unstemmed | Poly[diaquadi-μ-hydroxido-κ(4)
O:O-dinitrato-κ(4)
O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title_short | Poly[diaquadi-μ-hydroxido-κ(4)
O:O-dinitrato-κ(4)
O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)] |
title_sort | poly[diaquadi-μ-hydroxido-κ(4)
o:o-dinitrato-κ(4)
o:o′-bis[3-(pyridin-4-yl-κn)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343826/ https://www.ncbi.nlm.nih.gov/pubmed/22589800 http://dx.doi.org/10.1107/S1600536812010355 |
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