Cargando…
Bis(propane-1,3-diamine)disaccharinatonickel(II)
In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothiazol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which o...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343828/ https://www.ncbi.nlm.nih.gov/pubmed/22589802 http://dx.doi.org/10.1107/S1600536812010525 |
_version_ | 1782231853823950848 |
---|---|
author | Kaştaş, Gökhan Kocabıyık, Can |
author_facet | Kaştaş, Gökhan Kocabıyık, Can |
author_sort | Kaştaş, Gökhan |
collection | PubMed |
description | In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothiazol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which occupy trans positions, and four N atoms of the bidentate pen ligands to define a distorted octahedral geometry. The pen ligands chelate the metal ion, forming a six-membered ring which adopts a half-chair conformation, while the sac ligands adopt the most common coordination mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which form a one-dimensional network along [010]. It is also supported by an N—H⋯S hydrogen bond between the amine group of the pen ligand and the sulfonyl group of the sac ligand. |
format | Online Article Text |
id | pubmed-3343828 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438282012-05-15 Bis(propane-1,3-diamine)disaccharinatonickel(II) Kaştaş, Gökhan Kocabıyık, Can Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothiazol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which occupy trans positions, and four N atoms of the bidentate pen ligands to define a distorted octahedral geometry. The pen ligands chelate the metal ion, forming a six-membered ring which adopts a half-chair conformation, while the sac ligands adopt the most common coordination mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which form a one-dimensional network along [010]. It is also supported by an N—H⋯S hydrogen bond between the amine group of the pen ligand and the sulfonyl group of the sac ligand. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343828/ /pubmed/22589802 http://dx.doi.org/10.1107/S1600536812010525 Text en © Kaştaş and Kocabıyık 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kaştaş, Gökhan Kocabıyık, Can Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title | Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title_full | Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title_fullStr | Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title_full_unstemmed | Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title_short | Bis(propane-1,3-diamine)disaccharinatonickel(II) |
title_sort | bis(propane-1,3-diamine)disaccharinatonickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343828/ https://www.ncbi.nlm.nih.gov/pubmed/22589802 http://dx.doi.org/10.1107/S1600536812010525 |
work_keys_str_mv | AT kastasgokhan bispropane13diaminedisaccharinatonickelii AT kocabıyıkcan bispropane13diaminedisaccharinatonickelii |