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Bis(propane-1,3-diamine)­disaccharinatonickel(II)

In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothia­zol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which o...

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Autores principales: Kaştaş, Gökhan, Kocabıyık, Can
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343828/
https://www.ncbi.nlm.nih.gov/pubmed/22589802
http://dx.doi.org/10.1107/S1600536812010525
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author Kaştaş, Gökhan
Kocabıyık, Can
author_facet Kaştaş, Gökhan
Kocabıyık, Can
author_sort Kaştaş, Gökhan
collection PubMed
description In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothia­zol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which occupy trans positions, and four N atoms of the bidentate pen ligands to define a distorted octa­hedral geometry. The pen ligands chelate the metal ion, forming a six-membered ring which adopts a half-chair conformation, while the sac ligands adopt the most common coordination mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which form a one-dimensional network along [010]. It is also supported by an N—H⋯S hydrogen bond between the amine group of the pen ligand and the sulfonyl group of the sac ligand.
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spelling pubmed-33438282012-05-15 Bis(propane-1,3-diamine)­disaccharinatonickel(II) Kaştaş, Gökhan Kocabıyık, Can Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(7)H(4)NO(3)S)(2)(C(3)H(10)N(2))(2)] or [Ni(sac)(2)(pen)(2)] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ(6,2)-benzothia­zol-2-ide and pen = propane-1,3-diamine), the Ni(II) ion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which occupy trans positions, and four N atoms of the bidentate pen ligands to define a distorted octa­hedral geometry. The pen ligands chelate the metal ion, forming a six-membered ring which adopts a half-chair conformation, while the sac ligands adopt the most common coordination mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which form a one-dimensional network along [010]. It is also supported by an N—H⋯S hydrogen bond between the amine group of the pen ligand and the sulfonyl group of the sac ligand. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343828/ /pubmed/22589802 http://dx.doi.org/10.1107/S1600536812010525 Text en © Kaştaş and Kocabıyık 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kaştaş, Gökhan
Kocabıyık, Can
Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title_full Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title_fullStr Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title_full_unstemmed Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title_short Bis(propane-1,3-diamine)­disaccharinatonickel(II)
title_sort bis(propane-1,3-diamine)­disaccharinatonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343828/
https://www.ncbi.nlm.nih.gov/pubmed/22589802
http://dx.doi.org/10.1107/S1600536812010525
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