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Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)

In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa­hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two az...

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Detalles Bibliográficos
Autores principales: Wang, Kun-Miao, Liu, Zhi-Hua, Zheng, Qi, Liu, Chun-Bo, Miao, Ming-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343829/
https://www.ncbi.nlm.nih.gov/pubmed/22589803
http://dx.doi.org/10.1107/S160053681201046X
Descripción
Sumario:In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa­hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear mol­ecules are alternatively linked into layers parallel to the ac plane via N—H⋯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra­molecular framework by futher N—H⋯N hydrogen-bonding inter­actions.