Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)

In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa­hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two az...

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Autores principales: Wang, Kun-Miao, Liu, Zhi-Hua, Zheng, Qi, Liu, Chun-Bo, Miao, Ming-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343829/
https://www.ncbi.nlm.nih.gov/pubmed/22589803
http://dx.doi.org/10.1107/S160053681201046X
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author Wang, Kun-Miao
Liu, Zhi-Hua
Zheng, Qi
Liu, Chun-Bo
Miao, Ming-Ming
author_facet Wang, Kun-Miao
Liu, Zhi-Hua
Zheng, Qi
Liu, Chun-Bo
Miao, Ming-Ming
author_sort Wang, Kun-Miao
collection PubMed
description In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa­hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear mol­ecules are alternatively linked into layers parallel to the ac plane via N—H⋯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra­molecular framework by futher N—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-33438292012-05-15 Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II) Wang, Kun-Miao Liu, Zhi-Hua Zheng, Qi Liu, Chun-Bo Miao, Ming-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa­hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear mol­ecules are alternatively linked into layers parallel to the ac plane via N—H⋯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra­molecular framework by futher N—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343829/ /pubmed/22589803 http://dx.doi.org/10.1107/S160053681201046X Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Kun-Miao
Liu, Zhi-Hua
Zheng, Qi
Liu, Chun-Bo
Miao, Ming-Ming
Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title_full Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title_fullStr Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title_full_unstemmed Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title_short Bis(azido-κN)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) N (1),N (6)]manganese(II)
title_sort bis(azido-κn)bis­[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2) n (1),n (6)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343829/
https://www.ncbi.nlm.nih.gov/pubmed/22589803
http://dx.doi.org/10.1107/S160053681201046X
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