catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]

The N-heterocyclic ligand in the title compound, [Cu(NCS)(C(15)H(13)N(5)S(2))](n), coordinates to the Cu(I) atom through its pyridine N-donor site, and adjacent metal atoms are bridged by the thio­cyanate ion, forming a helical chain along the b axis. The geometry of the metal atom is tetra­hedral o...

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Detalles Bibliográficos
Autores principales: Peng, Rong, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343831/
https://www.ncbi.nlm.nih.gov/pubmed/22589805
http://dx.doi.org/10.1107/S160053681201063X
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author Peng, Rong
Ng, Seik Weng
author_facet Peng, Rong
Ng, Seik Weng
author_sort Peng, Rong
collection PubMed
description The N-heterocyclic ligand in the title compound, [Cu(NCS)(C(15)H(13)N(5)S(2))](n), coordinates to the Cu(I) atom through its pyridine N-donor site, and adjacent metal atoms are bridged by the thio­cyanate ion, forming a helical chain along the b axis. The geometry of the metal atom is tetra­hedral owing to a somewhat long intra­molecular Cu—S inter­action of 2.5621 (9) Å.
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spelling pubmed-33438312012-05-15 catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S] Peng, Rong Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The N-heterocyclic ligand in the title compound, [Cu(NCS)(C(15)H(13)N(5)S(2))](n), coordinates to the Cu(I) atom through its pyridine N-donor site, and adjacent metal atoms are bridged by the thio­cyanate ion, forming a helical chain along the b axis. The geometry of the metal atom is tetra­hedral owing to a somewhat long intra­molecular Cu—S inter­action of 2.5621 (9) Å. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343831/ /pubmed/22589805 http://dx.doi.org/10.1107/S160053681201063X Text en © Peng and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Rong
Ng, Seik Weng
catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_full catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_fullStr catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_full_unstemmed catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_short catena-Poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κS)meth­yl]pyridin-2-yl-κN}methyl­sulfan­yl)pyrimidine]­copper(I)]-μ-thio­cyanato-κ(2) N:S]
title_sort catena-poly[[[2-({6-[(pyrimidin-2-ylsulfanyl-κs)meth­yl]pyridin-2-yl-κn}methyl­sulfan­yl)pyrimidine]­copper(i)]-μ-thio­cyanato-κ(2) n:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343831/
https://www.ncbi.nlm.nih.gov/pubmed/22589805
http://dx.doi.org/10.1107/S160053681201063X
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AT ngseikweng catenapoly26pyrimidin2ylsulfanylksmethylpyridin2ylknmethylsulfanylpyrimidinecopperimthiocyanatok2ns

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