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Dichloridobis(2-phenylpyridine-κN)zinc(II)
In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenylpyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetrahedral coordination geometry. The dihedral angle between...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343833/ https://www.ncbi.nlm.nih.gov/pubmed/22589807 http://dx.doi.org/10.1107/S1600536812010616 |
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author | Dharmalingam, Sivanesan Lee, Ha-Jin Yoon, Sungho |
author_facet | Dharmalingam, Sivanesan Lee, Ha-Jin Yoon, Sungho |
author_sort | Dharmalingam, Sivanesan |
collection | PubMed |
description | In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenylpyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetrahedral coordination geometry. The dihedral angle between the phenyl ring and the metal-bound pyridine ring is 50.3 (4)° for each 2-phenylpyridine ligand. This arranges the phenyl ring from one ligand in the complex above the pyridine ring of the other resulting in an intramolecular π–π interaction, with a centroid–centroid distance of 3.6796 (17) Å. Weak C—H⋯Cl hydrogen bonds stabilize the crystal packing, linking molecules into chains along the c axis. |
format | Online Article Text |
id | pubmed-3343833 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438332012-05-15 Dichloridobis(2-phenylpyridine-κN)zinc(II) Dharmalingam, Sivanesan Lee, Ha-Jin Yoon, Sungho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenylpyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetrahedral coordination geometry. The dihedral angle between the phenyl ring and the metal-bound pyridine ring is 50.3 (4)° for each 2-phenylpyridine ligand. This arranges the phenyl ring from one ligand in the complex above the pyridine ring of the other resulting in an intramolecular π–π interaction, with a centroid–centroid distance of 3.6796 (17) Å. Weak C—H⋯Cl hydrogen bonds stabilize the crystal packing, linking molecules into chains along the c axis. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343833/ /pubmed/22589807 http://dx.doi.org/10.1107/S1600536812010616 Text en © Dharmalingam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dharmalingam, Sivanesan Lee, Ha-Jin Yoon, Sungho Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title | Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title_full | Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title_fullStr | Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title_full_unstemmed | Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title_short | Dichloridobis(2-phenylpyridine-κN)zinc(II) |
title_sort | dichloridobis(2-phenylpyridine-κn)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343833/ https://www.ncbi.nlm.nih.gov/pubmed/22589807 http://dx.doi.org/10.1107/S1600536812010616 |
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