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Dichloridobis(2-phenyl­pyridine-κN)zinc(II)

In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenyl­pyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetra­hedral coordination geometry. The dihedral angle between...

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Autores principales: Dharmalingam, Sivanesan, Lee, Ha-Jin, Yoon, Sungho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343833/
https://www.ncbi.nlm.nih.gov/pubmed/22589807
http://dx.doi.org/10.1107/S1600536812010616
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author Dharmalingam, Sivanesan
Lee, Ha-Jin
Yoon, Sungho
author_facet Dharmalingam, Sivanesan
Lee, Ha-Jin
Yoon, Sungho
author_sort Dharmalingam, Sivanesan
collection PubMed
description In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenyl­pyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetra­hedral coordination geometry. The dihedral angle between the phenyl ring and the metal-bound pyridine ring is 50.3 (4)° for each 2-phenyl­pyridine ligand. This arranges the phenyl ring from one ligand in the complex above the pyridine ring of the other resulting in an intra­molecular π–π inter­action, with a centroid–centroid distance of 3.6796 (17) Å. Weak C—H⋯Cl hydrogen bonds stabilize the crystal packing, linking mol­ecules into chains along the c axis.
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spelling pubmed-33438332012-05-15 Dichloridobis(2-phenyl­pyridine-κN)zinc(II) Dharmalingam, Sivanesan Lee, Ha-Jin Yoon, Sungho Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(11)H(9)N)(2)], the Zn(2+) cation lies on a twofold axis and is coordinated by two Cl(−) anions and the N atoms of two 2-phenyl­pyridine ligands, forming a ZnN(2)Cl(2) polyhedron with a slightly distorted tetra­hedral coordination geometry. The dihedral angle between the phenyl ring and the metal-bound pyridine ring is 50.3 (4)° for each 2-phenyl­pyridine ligand. This arranges the phenyl ring from one ligand in the complex above the pyridine ring of the other resulting in an intra­molecular π–π inter­action, with a centroid–centroid distance of 3.6796 (17) Å. Weak C—H⋯Cl hydrogen bonds stabilize the crystal packing, linking mol­ecules into chains along the c axis. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343833/ /pubmed/22589807 http://dx.doi.org/10.1107/S1600536812010616 Text en © Dharmalingam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dharmalingam, Sivanesan
Lee, Ha-Jin
Yoon, Sungho
Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title_full Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title_fullStr Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title_full_unstemmed Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title_short Dichloridobis(2-phenyl­pyridine-κN)zinc(II)
title_sort dichloridobis(2-phenyl­pyridine-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343833/
https://www.ncbi.nlm.nih.gov/pubmed/22589807
http://dx.doi.org/10.1107/S1600536812010616
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