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cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate
In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from the coordinated water molecules. The complex mole...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343834/ https://www.ncbi.nlm.nih.gov/pubmed/22589808 http://dx.doi.org/10.1107/S1600536812010446 |
| _version_ | 1782231855205974016 |
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| author | Tong, Shao-Wei Song, Wen-Dong Miao, Dong-Liang Li, Shi-Jie An, Jing-Bo |
| author_facet | Tong, Shao-Wei Song, Wen-Dong Miao, Dong-Liang Li, Shi-Jie An, Jing-Bo |
| author_sort | Tong, Shao-Wei |
| collection | PubMed |
| description | In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from the coordinated water molecules. The complex molecules are connected via water O—H⋯O and O—H⋯N hydrogen bonds and weak π–π stacking interactions between the benzene rings [minimum ring centroid separation = 3.750 (6) Å] into a three-dimensional polymeric structure. The imidazolyl group of the ligand is partially disordered over two sets of sites with refined occupancies of 0.531 (7):0.469 (7). |
| format | Online Article Text |
| id | pubmed-3343834 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438342012-05-15 cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate Tong, Shao-Wei Song, Wen-Dong Miao, Dong-Liang Li, Shi-Jie An, Jing-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from the coordinated water molecules. The complex molecules are connected via water O—H⋯O and O—H⋯N hydrogen bonds and weak π–π stacking interactions between the benzene rings [minimum ring centroid separation = 3.750 (6) Å] into a three-dimensional polymeric structure. The imidazolyl group of the ligand is partially disordered over two sets of sites with refined occupancies of 0.531 (7):0.469 (7). International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343834/ /pubmed/22589808 http://dx.doi.org/10.1107/S1600536812010446 Text en © Tong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tong, Shao-Wei Song, Wen-Dong Miao, Dong-Liang Li, Shi-Jie An, Jing-Bo cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN (3))phenyl]tetrazolido}manganese(II) dihydrate |
| title |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_full |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_fullStr |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_full_unstemmed |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_short |
cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN
(3))phenyl]tetrazolido}manganese(II) dihydrate |
| title_sort | cis-tetraaquabis{5-[4-(1h-imidazol-1-yl-κn
(3))phenyl]tetrazolido}manganese(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343834/ https://www.ncbi.nlm.nih.gov/pubmed/22589808 http://dx.doi.org/10.1107/S1600536812010446 |
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