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Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)

The distorted octa­hedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-m...

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Autores principales: Affan, Md. Abu, Salam, Md. Abdus, Jusoh, Ismail, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343835/
https://www.ncbi.nlm.nih.gov/pubmed/22589809
http://dx.doi.org/10.1107/S1600536812010902
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author Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description The distorted octa­hedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39 (8)°. Centrosymmetric dimers feature in the crystal packing mediated by N—H⋯S hydrogen bonds, leading to eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates are connected into a three-dimensional architecture by C—H⋯Cl and C—H⋯π inter­actions, as well as π–π inter­actions occurring between centrosymmetrically related pyridine rings [centroid–centroid distance = 3.6322 (13) Å].
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spelling pubmed-33438352012-05-15 Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV) Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The distorted octa­hedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39 (8)°. Centrosymmetric dimers feature in the crystal packing mediated by N—H⋯S hydrogen bonds, leading to eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates are connected into a three-dimensional architecture by C—H⋯Cl and C—H⋯π inter­actions, as well as π–π inter­actions occurring between centrosymmetrically related pyridine rings [centroid–centroid distance = 3.6322 (13) Å]. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343835/ /pubmed/22589809 http://dx.doi.org/10.1107/S1600536812010902 Text en © Affan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Salam, Md. Abdus
Jusoh, Ismail
Ng, Seik Weng
Tiekink, Edward R. T.
Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title_full Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title_fullStr Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title_full_unstemmed Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title_short Chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κN)ethyl­idene]thio­semicarbazidato-κ(2) N (1),S}diphenyl­tin(IV)
title_sort chlorido{4-cyclo­hexyl-1-[1-(pyridin-2-yl-κn)ethyl­idene]thio­semicarbazidato-κ(2) n (1),s}diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343835/
https://www.ncbi.nlm.nih.gov/pubmed/22589809
http://dx.doi.org/10.1107/S1600536812010902
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