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Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}diphenyltin(IV)
The distorted octahedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-m...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343835/ https://www.ncbi.nlm.nih.gov/pubmed/22589809 http://dx.doi.org/10.1107/S1600536812010902 |
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author | Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Affan, Md. Abu |
collection | PubMed |
description | The distorted octahedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39 (8)°. Centrosymmetric dimers feature in the crystal packing mediated by N—H⋯S hydrogen bonds, leading to eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates are connected into a three-dimensional architecture by C—H⋯Cl and C—H⋯π interactions, as well as π–π interactions occurring between centrosymmetrically related pyridine rings [centroid–centroid distance = 3.6322 (13) Å]. |
format | Online Article Text |
id | pubmed-3343835 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438352012-05-15 Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}diphenyltin(IV) Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The distorted octahedral geometry about the Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(14)H(19)N(4)S)Cl], is defined by the N,N,S-tridentate Schiff base ligand, two mutually trans ipso-C atoms of the Sn-bound phenyl groups, and the Cl atom which is trans to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39 (8)°. Centrosymmetric dimers feature in the crystal packing mediated by N—H⋯S hydrogen bonds, leading to eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates are connected into a three-dimensional architecture by C—H⋯Cl and C—H⋯π interactions, as well as π–π interactions occurring between centrosymmetrically related pyridine rings [centroid–centroid distance = 3.6322 (13) Å]. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343835/ /pubmed/22589809 http://dx.doi.org/10.1107/S1600536812010902 Text en © Affan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Affan, Md. Abu Salam, Md. Abdus Jusoh, Ismail Ng, Seik Weng Tiekink, Edward R. T. Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2) N (1),S}diphenyltin(IV) |
title | Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}diphenyltin(IV) |
title_full | Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}diphenyltin(IV) |
title_fullStr | Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}diphenyltin(IV) |
title_full_unstemmed | Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}diphenyltin(IV) |
title_short | Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ(2)
N
(1),S}diphenyltin(IV) |
title_sort | chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-κn)ethylidene]thiosemicarbazidato-κ(2)
n
(1),s}diphenyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343835/ https://www.ncbi.nlm.nih.gov/pubmed/22589809 http://dx.doi.org/10.1107/S1600536812010902 |
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