Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]

In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-di...

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Detalles Bibliográficos
Autores principales: Guo, Qian, Wang, Ping, Liu, Fu-Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343836/
https://www.ncbi.nlm.nih.gov/pubmed/22589810
http://dx.doi.org/10.1107/S1600536812008604
Descripción
Sumario:In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-dimethyl­pyridine ligands at the axial position of the Cu(II) ions. The dihedral angle between the two unique benzene rings is 84.26 (16)°. The dihedral angles between the pyridine ring and the benzene rings are 61.67 (15) and 34.27 (14)°. There is π–π stacking of inversion-related pyridine rings, with a centroid–centroid distance of 3.833 (2) Å.

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