Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]

In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-di...

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Detalles Bibliográficos
Autores principales: Guo, Qian, Wang, Ping, Liu, Fu-Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343836/
https://www.ncbi.nlm.nih.gov/pubmed/22589810
http://dx.doi.org/10.1107/S1600536812008604
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author Guo, Qian
Wang, Ping
Liu, Fu-Chen
author_facet Guo, Qian
Wang, Ping
Liu, Fu-Chen
author_sort Guo, Qian
collection PubMed
description In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-dimethyl­pyridine ligands at the axial position of the Cu(II) ions. The dihedral angle between the two unique benzene rings is 84.26 (16)°. The dihedral angles between the pyridine ring and the benzene rings are 61.67 (15) and 34.27 (14)°. There is π–π stacking of inversion-related pyridine rings, with a centroid–centroid distance of 3.833 (2) Å.
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spelling pubmed-33438362012-05-15 Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)] Guo, Qian Wang, Ping Liu, Fu-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(7)H(9)N)(2)], the Cu(II) atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two Cu(II) ions and four benzoate anions with two 3,5-dimethyl­pyridine ligands at the axial position of the Cu(II) ions. The dihedral angle between the two unique benzene rings is 84.26 (16)°. The dihedral angles between the pyridine ring and the benzene rings are 61.67 (15) and 34.27 (14)°. There is π–π stacking of inversion-related pyridine rings, with a centroid–centroid distance of 3.833 (2) Å. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343836/ /pubmed/22589810 http://dx.doi.org/10.1107/S1600536812008604 Text en © Guo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Qian
Wang, Ping
Liu, Fu-Chen
Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title_full Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title_fullStr Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title_full_unstemmed Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title_short Tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(II)]
title_sort tetra-μ-benzoato-bis­[(3,5-dimethyl­pyridine)­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343836/
https://www.ncbi.nlm.nih.gov/pubmed/22589810
http://dx.doi.org/10.1107/S1600536812008604
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AT wangping tetrambenzoatobis35dimethylpyridinecopperii
AT liufuchen tetrambenzoatobis35dimethylpyridinecopperii

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