Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate

The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl­anilinium cations, Cl(−) and [SbCl(5)](2−) anions and water mol­ecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2−) anions...

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Autor principal: Xu, Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343837/
https://www.ncbi.nlm.nih.gov/pubmed/22589811
http://dx.doi.org/10.1107/S1600536812009427
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author Xu, Qian
author_facet Xu, Qian
author_sort Xu, Qian
collection PubMed
description The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl­anilinium cations, Cl(−) and [SbCl(5)](2−) anions and water mol­ecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2−) anions related by an inversion center are joined by Sb⋯Cl inter­actions [Sb⋯Cl = 3.7273 (14) Å] into an [Sb(2)Cl(10)](4−) dimer with two bridging Cl atoms. The anions, water mol­ecules and ammonium groups of the cations are linked by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl­anilinium cations are packed between these layers.
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spelling pubmed-33438372012-05-15 Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate Xu, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl­anilinium cations, Cl(−) and [SbCl(5)](2−) anions and water mol­ecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2−) anions related by an inversion center are joined by Sb⋯Cl inter­actions [Sb⋯Cl = 3.7273 (14) Å] into an [Sb(2)Cl(10)](4−) dimer with two bridging Cl atoms. The anions, water mol­ecules and ammonium groups of the cations are linked by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl­anilinium cations are packed between these layers. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343837/ /pubmed/22589811 http://dx.doi.org/10.1107/S1600536812009427 Text en © Qian Xu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Qian
Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title_full Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title_fullStr Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title_full_unstemmed Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title_short Tris(4-methyl­anilinium) penta­chlorido­anti­monate(III) chloride monohydrate
title_sort tris(4-methyl­anilinium) penta­chlorido­anti­monate(iii) chloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343837/
https://www.ncbi.nlm.nih.gov/pubmed/22589811
http://dx.doi.org/10.1107/S1600536812009427
work_keys_str_mv AT xuqian tris4methylaniliniumpentachloridoantimonateiiichloridemonohydrate

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