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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium

In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth­oxy­benzoate anions in a distorted octa­hedral environment. Two O atoms of one bidentate 2-meth­oxy­benz...

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Detalles Bibliográficos
Autores principales: Zhang, Heng, Zhao, Pei-Zheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343841/
https://www.ncbi.nlm.nih.gov/pubmed/22589815
http://dx.doi.org/10.1107/S1600536812010835
Descripción
Sumario:In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth­oxy­benzoate anions in a distorted octa­hedral environment. Two O atoms of one bidentate 2-meth­oxy­benzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking inter­actions between the dmphen rings of neighboring mol­ecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å.