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(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium

In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth­oxy­benzoate anions in a distorted octa­hedral environment. Two O atoms of one bidentate 2-meth­oxy­benz...

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Autores principales: Zhang, Heng, Zhao, Pei-Zheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343841/
https://www.ncbi.nlm.nih.gov/pubmed/22589815
http://dx.doi.org/10.1107/S1600536812010835
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author Zhang, Heng
Zhao, Pei-Zheng
author_facet Zhang, Heng
Zhao, Pei-Zheng
author_sort Zhang, Heng
collection PubMed
description In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth­oxy­benzoate anions in a distorted octa­hedral environment. Two O atoms of one bidentate 2-meth­oxy­benzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking inter­actions between the dmphen rings of neighboring mol­ecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å.
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spelling pubmed-33438412012-05-15 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium Zhang, Heng Zhao, Pei-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-meth­oxy­benzoate anions in a distorted octa­hedral environment. Two O atoms of one bidentate 2-meth­oxy­benzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking inter­actions between the dmphen rings of neighboring mol­ecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343841/ /pubmed/22589815 http://dx.doi.org/10.1107/S1600536812010835 Text en © Zhang and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Heng
Zhao, Pei-Zheng
(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title_full (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title_fullStr (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title_full_unstemmed (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title_short (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(2-meth­oxy­benzoato-κ(2) O (1),O (1′))cadmium
title_sort (2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)bis­(2-meth­oxy­benzoato-κ(2) o (1),o (1′))cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343841/
https://www.ncbi.nlm.nih.gov/pubmed/22589815
http://dx.doi.org/10.1107/S1600536812010835
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