Cargando…
(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-methoxybenzoato-κ(2) O (1),O (1′))cadmium
In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenz...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343841/ https://www.ncbi.nlm.nih.gov/pubmed/22589815 http://dx.doi.org/10.1107/S1600536812010835 |
_version_ | 1782231856929832960 |
---|---|
author | Zhang, Heng Zhao, Pei-Zheng |
author_facet | Zhang, Heng Zhao, Pei-Zheng |
author_sort | Zhang, Heng |
collection | PubMed |
description | In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking interactions between the dmphen rings of neighboring molecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å. |
format | Online Article Text |
id | pubmed-3343841 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438412012-05-15 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-methoxybenzoato-κ(2) O (1),O (1′))cadmium Zhang, Heng Zhao, Pei-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(7)O(3))(2)(C(14)H(12)N(2))], the Cd(II) ion is coordinated by two N atoms from a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and four O atoms from two 2-methoxybenzoate anions in a distorted octahedral environment. Two O atoms of one bidentate 2-methoxybenzoate ligand are each disordered over two positions, with site-occupancy factors of 0.579 (4) and 0.421 (4). In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming a two-dimensional network lieing parallel to the bc plane. The crystal packing is further stablized by π–π stacking interactions between the dmphen rings of neighboring molecules, with distances between their parallel dmphen ring planes of 3.517 (3) and 3.610 (3) Å. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343841/ /pubmed/22589815 http://dx.doi.org/10.1107/S1600536812010835 Text en © Zhang and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Heng Zhao, Pei-Zheng (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(2-methoxybenzoato-κ(2) O (1),O (1′))cadmium |
title | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-methoxybenzoato-κ(2)
O
(1),O
(1′))cadmium |
title_full | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-methoxybenzoato-κ(2)
O
(1),O
(1′))cadmium |
title_fullStr | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-methoxybenzoato-κ(2)
O
(1),O
(1′))cadmium |
title_full_unstemmed | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-methoxybenzoato-κ(2)
O
(1),O
(1′))cadmium |
title_short | (2,9-Dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(2-methoxybenzoato-κ(2)
O
(1),O
(1′))cadmium |
title_sort | (2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)bis(2-methoxybenzoato-κ(2)
o
(1),o
(1′))cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343841/ https://www.ncbi.nlm.nih.gov/pubmed/22589815 http://dx.doi.org/10.1107/S1600536812010835 |
work_keys_str_mv | AT zhangheng 29dimethyl110phenanthrolinek2nnbis2methoxybenzoatok2o1o1cadmium AT zhaopeizheng 29dimethyl110phenanthrolinek2nnbis2methoxybenzoatok2o1o1cadmium |