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Poly[tetraaquabis(μ(3)-oxalato-κ(5) O (1),O (2):O (1′):O (1′),O (2′))(μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′))dipraseodymium(III)]
In the title complex, [Pr(2)(C(2)O(4))(3)(H(2)O)(4)](n), the two independent Pr(III) ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The Pr(III) ions are bridged by the oxalate ligands, formi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343842/ https://www.ncbi.nlm.nih.gov/pubmed/22589816 http://dx.doi.org/10.1107/S1600536812011014 |
| _version_ | 1782231857161568256 |
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| author | Hao, Cheng-Jun Xie, Hui |
| author_facet | Hao, Cheng-Jun Xie, Hui |
| author_sort | Hao, Cheng-Jun |
| collection | PubMed |
| description | In the title complex, [Pr(2)(C(2)O(4))(3)(H(2)O)(4)](n), the two independent Pr(III) ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The Pr(III) ions are bridged by the oxalate ligands, forming a layer parallel to (001). O—H⋯O hydrogen bonds connect the layers. |
| format | Online Article Text |
| id | pubmed-3343842 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438422012-05-15 Poly[tetraaquabis(μ(3)-oxalato-κ(5) O (1),O (2):O (1′):O (1′),O (2′))(μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′))dipraseodymium(III)] Hao, Cheng-Jun Xie, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pr(2)(C(2)O(4))(3)(H(2)O)(4)](n), the two independent Pr(III) ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The Pr(III) ions are bridged by the oxalate ligands, forming a layer parallel to (001). O—H⋯O hydrogen bonds connect the layers. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343842/ /pubmed/22589816 http://dx.doi.org/10.1107/S1600536812011014 Text en © Hao and Xie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hao, Cheng-Jun Xie, Hui Poly[tetraaquabis(μ(3)-oxalato-κ(5) O (1),O (2):O (1′):O (1′),O (2′))(μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′))dipraseodymium(III)] |
| title | Poly[tetraaquabis(μ(3)-oxalato-κ(5)
O
(1),O
(2):O
(1′):O
(1′),O
(2′))(μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′))dipraseodymium(III)] |
| title_full | Poly[tetraaquabis(μ(3)-oxalato-κ(5)
O
(1),O
(2):O
(1′):O
(1′),O
(2′))(μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′))dipraseodymium(III)] |
| title_fullStr | Poly[tetraaquabis(μ(3)-oxalato-κ(5)
O
(1),O
(2):O
(1′):O
(1′),O
(2′))(μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′))dipraseodymium(III)] |
| title_full_unstemmed | Poly[tetraaquabis(μ(3)-oxalato-κ(5)
O
(1),O
(2):O
(1′):O
(1′),O
(2′))(μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′))dipraseodymium(III)] |
| title_short | Poly[tetraaquabis(μ(3)-oxalato-κ(5)
O
(1),O
(2):O
(1′):O
(1′),O
(2′))(μ(2)-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′))dipraseodymium(III)] |
| title_sort | poly[tetraaquabis(μ(3)-oxalato-κ(5)
o
(1),o
(2):o
(1′):o
(1′),o
(2′))(μ(2)-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′))dipraseodymium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343842/ https://www.ncbi.nlm.nih.gov/pubmed/22589816 http://dx.doi.org/10.1107/S1600536812011014 |
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