catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]

In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Cu(OH(2))(3)O(...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Gao, Yue, Xu, Yue, Qin, Xiao-lin, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343843/
https://www.ncbi.nlm.nih.gov/pubmed/22589817
http://dx.doi.org/10.1107/S1600536812010161
Descripción
Sumario:In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Cu(OH(2))(3)O(4) cluster displays a penta­gonal bipyrimadal geometry with two weak coordinations [Cu—O(furan) = 2.790 (2) Å) and Cu—O(carboxyl­ate) = 2.684 (2) Å] and two water mol­ecules located in axial positions.

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