catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]

In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Cu(OH(2))(3)O(...

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Autores principales: Li, Ya-Feng, Gao, Yue, Xu, Yue, Qin, Xiao-lin, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343843/
https://www.ncbi.nlm.nih.gov/pubmed/22589817
http://dx.doi.org/10.1107/S1600536812010161
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author Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-lin
Gao, Wen-Yuan
author_facet Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-lin
Gao, Wen-Yuan
author_sort Li, Ya-Feng
collection PubMed
description In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Cu(OH(2))(3)O(4) cluster displays a penta­gonal bipyrimadal geometry with two weak coordinations [Cu—O(furan) = 2.790 (2) Å) and Cu—O(carboxyl­ate) = 2.684 (2) Å] and two water mol­ecules located in axial positions.
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spelling pubmed-33438432012-05-15 catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)] Li, Ya-Feng Gao, Yue Xu, Yue Qin, Xiao-lin Gao, Wen-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Cu(OH(2))(3)O(4) cluster with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Cu(OH(2))(3)O(4) cluster displays a penta­gonal bipyrimadal geometry with two weak coordinations [Cu—O(furan) = 2.790 (2) Å) and Cu—O(carboxyl­ate) = 2.684 (2) Å] and two water mol­ecules located in axial positions. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343843/ /pubmed/22589817 http://dx.doi.org/10.1107/S1600536812010161 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-lin
Gao, Wen-Yuan
catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title_full catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title_fullStr catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title_full_unstemmed catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title_short catena-Poly[[triaquacopper(II)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) O (1),O (2):O (2),O (2′)]
title_sort catena-poly[[triaquacopper(ii)]-μ(2)-furan-2,5-dicarboxyl­ato-κ(4) o (1),o (2):o (2),o (2′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343843/
https://www.ncbi.nlm.nih.gov/pubmed/22589817
http://dx.doi.org/10.1107/S1600536812010161
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