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Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)

In the title complex, [Pt(N(3))(4)(C(10)H(9)N(3))], the Pt(IV) ion is six-coordinated in a slightly distorted octa­hedral environment by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343845/
https://www.ncbi.nlm.nih.gov/pubmed/22589819
http://dx.doi.org/10.1107/S1600536812011178
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [Pt(N(3))(4)(C(10)H(9)N(3))], the Pt(IV) ion is six-coordinated in a slightly distorted octa­hedral environment by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 20.0 (3)°. The azide ligands are slightly bent [N—N—N = 173.5 (8)–175.1 (8)°]. In the crystal, the complex mol­ecules are connected by N—H⋯N hydrogen bonds, forming a chain along the b axis. An inter­molecular π–π inter­action between the chains is also present, the ring centroid–centroid distance being 3.713 (4) Å.
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spelling pubmed-33438452012-05-15 Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pt(N(3))(4)(C(10)H(9)N(3))], the Pt(IV) ion is six-coordinated in a slightly distorted octa­hedral environment by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and four N atoms from four azide anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 20.0 (3)°. The azide ligands are slightly bent [N—N—N = 173.5 (8)–175.1 (8)°]. In the crystal, the complex mol­ecules are connected by N—H⋯N hydrogen bonds, forming a chain along the b axis. An inter­molecular π–π inter­action between the chains is also present, the ring centroid–centroid distance being 3.713 (4) Å. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343845/ /pubmed/22589819 http://dx.doi.org/10.1107/S1600536812011178 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title_full Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title_fullStr Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title_full_unstemmed Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title_short Tetra­kis(azido-κN)(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(IV)
title_sort tetra­kis(azido-κn)(di-2-pyridyl­amine-κ(2) n (2),n (2′))platinum(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343845/
https://www.ncbi.nlm.nih.gov/pubmed/22589819
http://dx.doi.org/10.1107/S1600536812011178
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