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(8-Aminoquinoline-κ(2) N,N′)bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)cobalt(II)
In the title compound, [Co(C(5)HF(6)O(2))(2)(C(9)H(8)N(2))], the Co(II) centre exhibits a pseudooctahedral coordination geometry, comprising two N-atom donors from the bidentate aminoquinoline ligand and four O-atom donor atoms from two bidentate chelating 1,1,1,5,5,5-hexafluoropentane-2,4-dionate...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343848/ https://www.ncbi.nlm.nih.gov/pubmed/22589822 http://dx.doi.org/10.1107/S1600536812011312 |
Sumario: | In the title compound, [Co(C(5)HF(6)O(2))(2)(C(9)H(8)N(2))], the Co(II) centre exhibits a pseudooctahedral coordination geometry, comprising two N-atom donors from the bidentate aminoquinoline ligand and four O-atom donor atoms from two bidentate chelating 1,1,1,5,5,5-hexafluoropentane-2,4-dionate ligands. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers. These dimers are further connected through π–π interactions between neighbouring quinoline rings [centroid–centroid distance = 3.472 (2) Å], and stack along the c axis. |
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