(8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)

In the title compound, [Co(C(5)HF(6)O(2))(2)(C(9)H(8)N(2))], the Co(II) centre exhibits a pseudooctahedral coordination geometry, comprising two N-atom donors from the bidentate amino­quinoline ligand and four O-atom donor atoms from two bidentate chelating 1,1,1,5,5,5-hexafluoropentane-2,4-dionate...

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Detalles Bibliográficos
Autores principales: Harding, David J., Sertphon, Darunee, Harding, Phimphaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343848/
https://www.ncbi.nlm.nih.gov/pubmed/22589822
http://dx.doi.org/10.1107/S1600536812011312
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author Harding, David J.
Sertphon, Darunee
Harding, Phimphaka
author_facet Harding, David J.
Sertphon, Darunee
Harding, Phimphaka
author_sort Harding, David J.
collection PubMed
description In the title compound, [Co(C(5)HF(6)O(2))(2)(C(9)H(8)N(2))], the Co(II) centre exhibits a pseudooctahedral coordination geometry, comprising two N-atom donors from the bidentate amino­quinoline ligand and four O-atom donor atoms from two bidentate chelating 1,1,1,5,5,5-hexafluoropentane-2,4-dionate ligands. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers. These dimers are further connected through π–π interactions between neighbouring quinoline rings [centroid–centroid distance = 3.472 (2) Å], and stack along the c axis.
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spelling pubmed-33438482012-05-15 (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II) Harding, David J. Sertphon, Darunee Harding, Phimphaka Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)HF(6)O(2))(2)(C(9)H(8)N(2))], the Co(II) centre exhibits a pseudooctahedral coordination geometry, comprising two N-atom donors from the bidentate amino­quinoline ligand and four O-atom donor atoms from two bidentate chelating 1,1,1,5,5,5-hexafluoropentane-2,4-dionate ligands. In the crystal, molecules are linked via pairs of N—H⋯O hydrogen bonds, forming inversion dimers. These dimers are further connected through π–π interactions between neighbouring quinoline rings [centroid–centroid distance = 3.472 (2) Å], and stack along the c axis. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343848/ /pubmed/22589822 http://dx.doi.org/10.1107/S1600536812011312 Text en © Harding et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harding, David J.
Sertphon, Darunee
Harding, Phimphaka
(8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_full (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_fullStr (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_full_unstemmed (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_short (8-Amino­quinoline-κ(2) N,N′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_sort (8-amino­quinoline-κ(2) n,n′)bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) o,o′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343848/
https://www.ncbi.nlm.nih.gov/pubmed/22589822
http://dx.doi.org/10.1107/S1600536812011312
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