Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)

The Pt(II) ion in the title complex, [PtBr(2)(C(10)H(9)N(3))], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridyl­amine (dpa) ligand and two Br(−) anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343850/
https://www.ncbi.nlm.nih.gov/pubmed/22589824
http://dx.doi.org/10.1107/S1600536812011300
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pt(II) ion in the title complex, [PtBr(2)(C(10)H(9)N(3))], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridyl­amine (dpa) ligand and two Br(−) anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being 40.8 (2)°. The complex mol­ecules are stacked in columns along [001] through π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.437 (3) and 3.520 (3) Å]. Inter­molecular N—H⋯Br hydrogen bonds connect the mol­ecules into chains running along [010]. Intra­molecular C—H⋯Br interactions are also observed.
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spelling pubmed-33438502012-05-15 Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtBr(2)(C(10)H(9)N(3))], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridyl­amine (dpa) ligand and two Br(−) anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being 40.8 (2)°. The complex mol­ecules are stacked in columns along [001] through π–π inter­actions between the pyridine rings [centroid–centroid distances = 3.437 (3) and 3.520 (3) Å]. Inter­molecular N—H⋯Br hydrogen bonds connect the mol­ecules into chains running along [010]. Intra­molecular C—H⋯Br interactions are also observed. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343850/ /pubmed/22589824 http://dx.doi.org/10.1107/S1600536812011300 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title_full Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title_fullStr Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title_full_unstemmed Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title_short Dibromido(di-2-pyridyl­amine-κ(2) N (2),N (2′))platinum(II)
title_sort dibromido(di-2-pyridyl­amine-κ(2) n (2),n (2′))platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343850/
https://www.ncbi.nlm.nih.gov/pubmed/22589824
http://dx.doi.org/10.1107/S1600536812011300
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