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(Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))palladium(II)
In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands ar...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343851/ https://www.ncbi.nlm.nih.gov/pubmed/22589825 http://dx.doi.org/10.1107/S1600536812011385 |
Sumario: | In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) Å in dipic and 0.091 (4) Å in acr] and the dihedral angle between their mean planes is 58.67 (7)°. The Pd—O bond lengths are nearly equal, but the Pd—N bond lengths are slightly different. There is a short C—H⋯O interaction in the molecule involving the two ligands. In the crystal, complex molecules are linked through C—H⋯O interactions, forming a three-dimensional network. There are also a number of intermolecular π–π interactions present, the shortest ring centroid–centroid distance being 3.622 (3) Å. |
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