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(Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)

In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxyl­ate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands ar...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343851/
https://www.ncbi.nlm.nih.gov/pubmed/22589825
http://dx.doi.org/10.1107/S1600536812011385
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxyl­ate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) Å in dipic and 0.091 (4) Å in acr] and the dihedral angle between their mean planes is 58.67 (7)°. The Pd—O bond lengths are nearly equal, but the Pd—N bond lengths are slightly different. There is a short C—H⋯O inter­action in the mol­ecule involving the two ligands. In the crystal, complex mol­ecules are linked through C—H⋯O inter­actions, forming a three-dimensional network. There are also a number of inter­molecular π–π inter­actions present, the shortest ring centroid–centroid distance being 3.622 (3) Å.
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spelling pubmed-33438512012-05-15 (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxyl­ate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) Å in dipic and 0.091 (4) Å in acr] and the dihedral angle between their mean planes is 58.67 (7)°. The Pd—O bond lengths are nearly equal, but the Pd—N bond lengths are slightly different. There is a short C—H⋯O inter­action in the mol­ecule involving the two ligands. In the crystal, complex mol­ecules are linked through C—H⋯O inter­actions, forming a three-dimensional network. There are also a number of inter­molecular π–π inter­actions present, the shortest ring centroid–centroid distance being 3.622 (3) Å. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343851/ /pubmed/22589825 http://dx.doi.org/10.1107/S1600536812011385 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title_full (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title_fullStr (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title_full_unstemmed (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title_short (Acridine-κN)(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))palladium(II)
title_sort (acridine-κn)(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343851/
https://www.ncbi.nlm.nih.gov/pubmed/22589825
http://dx.doi.org/10.1107/S1600536812011385
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