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(Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))palladium(II)
In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands ar...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343851/ https://www.ncbi.nlm.nih.gov/pubmed/22589825 http://dx.doi.org/10.1107/S1600536812011385 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) Å in dipic and 0.091 (4) Å in acr] and the dihedral angle between their mean planes is 58.67 (7)°. The Pd—O bond lengths are nearly equal, but the Pd—N bond lengths are slightly different. There is a short C—H⋯O interaction in the molecule involving the two ligands. In the crystal, complex molecules are linked through C—H⋯O interactions, forming a three-dimensional network. There are also a number of intermolecular π–π interactions present, the shortest ring centroid–centroid distance being 3.622 (3) Å. |
format | Online Article Text |
id | pubmed-3343851 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438512012-05-15 (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(C(7)H(3)NO(4))(C(13)H(9)N)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by one N and two O atoms from the tridentate pyridine-2,6-dicarboxylate (dipic) anionic ligand and one N atom of the acridine (acr) ligand. The dipic and acr ligands are nearly planar [maximum deviation = 0.069 (3) Å in dipic and 0.091 (4) Å in acr] and the dihedral angle between their mean planes is 58.67 (7)°. The Pd—O bond lengths are nearly equal, but the Pd—N bond lengths are slightly different. There is a short C—H⋯O interaction in the molecule involving the two ligands. In the crystal, complex molecules are linked through C—H⋯O interactions, forming a three-dimensional network. There are also a number of intermolecular π–π interactions present, the shortest ring centroid–centroid distance being 3.622 (3) Å. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343851/ /pubmed/22589825 http://dx.doi.org/10.1107/S1600536812011385 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))palladium(II) |
title | (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))palladium(II) |
title_full | (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))palladium(II) |
title_fullStr | (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))palladium(II) |
title_full_unstemmed | (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))palladium(II) |
title_short | (Acridine-κN)(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))palladium(II) |
title_sort | (acridine-κn)(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343851/ https://www.ncbi.nlm.nih.gov/pubmed/22589825 http://dx.doi.org/10.1107/S1600536812011385 |
work_keys_str_mv | AT hakwang acridineknpyridine26dicarboxylatok3o2no6palladiumii |