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Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) dimethylformamide monosolvate
In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343852/ https://www.ncbi.nlm.nih.gov/pubmed/22589826 http://dx.doi.org/10.1107/S1600536812011324 |
| _version_ | 1782231859851165696 |
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| author | Wei, Yun Pang, Ting Liu, Jiacheng Li, Meng Liang, Lili |
| author_facet | Wei, Yun Pang, Ting Liu, Jiacheng Li, Meng Liang, Lili |
| author_sort | Wei, Yun |
| collection | PubMed |
| description | In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethylformamide (DMF) monosolvate. In the crystal, complex molecules are linked via O—H(water)⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H⋯Cl interaction, and the DMF molecule is linked to the complex molecule by C—H⋯O interactions. |
| format | Online Article Text |
| id | pubmed-3343852 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438522012-05-15 Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) dimethylformamide monosolvate Wei, Yun Pang, Ting Liu, Jiacheng Li, Meng Liang, Lili Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetradentate 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethylformamide (DMF) monosolvate. In the crystal, complex molecules are linked via O—H(water)⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H⋯Cl interaction, and the DMF molecule is linked to the complex molecule by C—H⋯O interactions. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343852/ /pubmed/22589826 http://dx.doi.org/10.1107/S1600536812011324 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wei, Yun Pang, Ting Liu, Jiacheng Li, Meng Liang, Lili Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) dimethylformamide monosolvate |
| title | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) dimethylformamide monosolvate |
| title_full | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) dimethylformamide monosolvate |
| title_fullStr | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) dimethylformamide monosolvate |
| title_full_unstemmed | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) dimethylformamide monosolvate |
| title_short | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) dimethylformamide monosolvate |
| title_sort | aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(2)
o
(1),n,n′,o
(1′)}cobalt(iii) dimethylformamide monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343852/ https://www.ncbi.nlm.nih.gov/pubmed/22589826 http://dx.doi.org/10.1107/S1600536812011324 |
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