Tetra­kis(nitrato-κ(2) O,O′)[N,N′-1,4-phenyl­enebis(pyridine-4-carboxamide)-κN (1)](4-{[4-(pyridine-4-carboxamido-κN (1))phen­yl]carbamo­yl}pyridin-1-ium)neodymium(III)

In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-anti­prismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters...

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Detalles Bibliográficos
Autores principales: Zhang, Yun, Hao, Jiao-Jiao, Zhou, Hu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343854/
https://www.ncbi.nlm.nih.gov/pubmed/22589828
http://dx.doi.org/10.1107/S1600536812011397
Descripción
Sumario:In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-anti­prismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters are linked through N—H⋯O and N—H⋯N hydrogen-bonding inter­actions, generating layers in the (102) plane.

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