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Tetrakis(nitrato-κ(2) O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN (1)](4-{[4-(pyridine-4-carboxamido-κN (1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III)
In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-antiprismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343854/ https://www.ncbi.nlm.nih.gov/pubmed/22589828 http://dx.doi.org/10.1107/S1600536812011397 |
| _version_ | 1782231860293664768 |
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| author | Zhang, Yun Hao, Jiao-Jiao Zhou, Hu |
| author_facet | Zhang, Yun Hao, Jiao-Jiao Zhou, Hu |
| author_sort | Zhang, Yun |
| collection | PubMed |
| description | In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-antiprismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters are linked through N—H⋯O and N—H⋯N hydrogen-bonding interactions, generating layers in the (102) plane. |
| format | Online Article Text |
| id | pubmed-3343854 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438542012-05-15 Tetrakis(nitrato-κ(2) O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN (1)](4-{[4-(pyridine-4-carboxamido-κN (1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) Zhang, Yun Hao, Jiao-Jiao Zhou, Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-antiprismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters are linked through N—H⋯O and N—H⋯N hydrogen-bonding interactions, generating layers in the (102) plane. International Union of Crystallography 2012-03-21 /pmc/articles/PMC3343854/ /pubmed/22589828 http://dx.doi.org/10.1107/S1600536812011397 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Yun Hao, Jiao-Jiao Zhou, Hu Tetrakis(nitrato-κ(2) O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN (1)](4-{[4-(pyridine-4-carboxamido-κN (1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title | Tetrakis(nitrato-κ(2)
O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN
(1)](4-{[4-(pyridine-4-carboxamido-κN
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title_full | Tetrakis(nitrato-κ(2)
O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN
(1)](4-{[4-(pyridine-4-carboxamido-κN
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title_fullStr | Tetrakis(nitrato-κ(2)
O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN
(1)](4-{[4-(pyridine-4-carboxamido-κN
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title_full_unstemmed | Tetrakis(nitrato-κ(2)
O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN
(1)](4-{[4-(pyridine-4-carboxamido-κN
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title_short | Tetrakis(nitrato-κ(2)
O,O′)[N,N′-1,4-phenylenebis(pyridine-4-carboxamide)-κN
(1)](4-{[4-(pyridine-4-carboxamido-κN
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(III) |
| title_sort | tetrakis(nitrato-κ(2)
o,o′)[n,n′-1,4-phenylenebis(pyridine-4-carboxamide)-κn
(1)](4-{[4-(pyridine-4-carboxamido-κn
(1))phenyl]carbamoyl}pyridin-1-ium)neodymium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343854/ https://www.ncbi.nlm.nih.gov/pubmed/22589828 http://dx.doi.org/10.1107/S1600536812011397 |
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