[(4-Methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κS)copper(II) dichloro­methane hemisolvate

The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol­ecules (A and B) in the asymmetric unit, accompanied by one dichloro­methane solvent mol­ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three fro...

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Detalles Bibliográficos
Autores principales: Qi, Yan, Li, Yang, Ma, Zheng-Ping, Chen, Qiu-Yun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343859/
https://www.ncbi.nlm.nih.gov/pubmed/22589833
http://dx.doi.org/10.1107/S1600536812011476
Descripción
Sumario:The title compound, [Cu(NCS)(2)(C(20)H(21)N(3))]·0.5CH(2)Cl(2), crystallized with two independent complex mol­ecules (A and B) in the asymmetric unit, accompanied by one dichloro­methane solvent mol­ecule. Each Cu(II) atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine ligand and two from the thio­cyanate ligands. In the crystal, the B mol­ecules are linked via C—H⋯S inter­actions, forming chains propagating along [100].

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