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Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II)
In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxylate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343860/ https://www.ncbi.nlm.nih.gov/pubmed/22589834 http://dx.doi.org/10.1107/S1600536812009919 |
Sumario: | In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxylate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the mean planes of the pyridine (py) ring and the carboxylate group is 74.71 (7)°. The dihedral angles between the planar CuN(2)O(2) core and the py ring and carboxylate plane are 67.72 (5) and 89.95 (5)°, respectively. Based on the refined C=C and C—C bond lengths, the terminal =CH(2) and –CH(3) groups of the carboxylate anion may be disordered, but the disorder could not be resolved in the present experiment. Several intramolecular C—H⋯O interactions occur. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, generating chains propagating in [100]. |
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