Cargando…

Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)

In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxyl­ate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the...

Descripción completa

Detalles Bibliográficos
Autores principales: Ejaz, Khan, Islam Ullah, Murtaza, Alina, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343860/
https://www.ncbi.nlm.nih.gov/pubmed/22589834
http://dx.doi.org/10.1107/S1600536812009919
_version_ 1782231861673590784
author Ejaz,
Khan, Islam Ullah
Murtaza, Alina
Harrison, William T. A.
author_facet Ejaz,
Khan, Islam Ullah
Murtaza, Alina
Harrison, William T. A.
author_sort Ejaz,
collection PubMed
description In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxyl­ate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the mean planes of the pyridine (py) ring and the carboxyl­ate group is 74.71 (7)°. The dihedral angles between the planar CuN(2)O(2) core and the py ring and carboxyl­ate plane are 67.72 (5) and 89.95 (5)°, respectively. Based on the refined C=C and C—C bond lengths, the terminal =CH(2) and –CH(3) groups of the carboxyl­ate anion may be disordered, but the disorder could not be resolved in the present experiment. Several intra­molecular C—H⋯O inter­actions occur. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, generating chains propagating in [100].
format Online
Article
Text
id pubmed-3343860
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33438602012-05-15 Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II) Ejaz, Khan, Islam Ullah Murtaza, Alina Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxyl­ate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the mean planes of the pyridine (py) ring and the carboxyl­ate group is 74.71 (7)°. The dihedral angles between the planar CuN(2)O(2) core and the py ring and carboxyl­ate plane are 67.72 (5) and 89.95 (5)°, respectively. Based on the refined C=C and C—C bond lengths, the terminal =CH(2) and –CH(3) groups of the carboxyl­ate anion may be disordered, but the disorder could not be resolved in the present experiment. Several intra­molecular C—H⋯O inter­actions occur. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, generating chains propagating in [100]. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343860/ /pubmed/22589834 http://dx.doi.org/10.1107/S1600536812009919 Text en © Ejaz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ejaz,
Khan, Islam Ullah
Murtaza, Alina
Harrison, William T. A.
Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title_full Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title_fullStr Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title_full_unstemmed Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title_short Bis(methacrylato-κO)bis­(2,4,6-trimethyl­pyridine-κN)copper(II)
title_sort bis(methacrylato-κo)bis­(2,4,6-trimethyl­pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343860/
https://www.ncbi.nlm.nih.gov/pubmed/22589834
http://dx.doi.org/10.1107/S1600536812009919
work_keys_str_mv AT ejaz bismethacrylatokobis246trimethylpyridinekncopperii
AT khanislamullah bismethacrylatokobis246trimethylpyridinekncopperii
AT murtazaalina bismethacrylatokobis246trimethylpyridinekncopperii
AT harrisonwilliamta bismethacrylatokobis246trimethylpyridinekncopperii