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Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II)
In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxylate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343860/ https://www.ncbi.nlm.nih.gov/pubmed/22589834 http://dx.doi.org/10.1107/S1600536812009919 |
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author | Ejaz, Khan, Islam Ullah Murtaza, Alina Harrison, William T. A. |
author_facet | Ejaz, Khan, Islam Ullah Murtaza, Alina Harrison, William T. A. |
author_sort | Ejaz, |
collection | PubMed |
description | In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxylate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the mean planes of the pyridine (py) ring and the carboxylate group is 74.71 (7)°. The dihedral angles between the planar CuN(2)O(2) core and the py ring and carboxylate plane are 67.72 (5) and 89.95 (5)°, respectively. Based on the refined C=C and C—C bond lengths, the terminal =CH(2) and –CH(3) groups of the carboxylate anion may be disordered, but the disorder could not be resolved in the present experiment. Several intramolecular C—H⋯O interactions occur. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, generating chains propagating in [100]. |
format | Online Article Text |
id | pubmed-3343860 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438602012-05-15 Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) Ejaz, Khan, Islam Ullah Murtaza, Alina Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the monomeric title complex, [Cu(C(4)H(5)O(2))(2)(C(8)H(11)N)(2)], the Cu(II) atom lies on a centre of inversion. Its coordination by two substituted pyridine ligands and two carboxylate anions leads to a slightly distorted trans-CuN(2)O(2) square-planar geometry. The dihedral angle between the mean planes of the pyridine (py) ring and the carboxylate group is 74.71 (7)°. The dihedral angles between the planar CuN(2)O(2) core and the py ring and carboxylate plane are 67.72 (5) and 89.95 (5)°, respectively. Based on the refined C=C and C—C bond lengths, the terminal =CH(2) and –CH(3) groups of the carboxylate anion may be disordered, but the disorder could not be resolved in the present experiment. Several intramolecular C—H⋯O interactions occur. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, generating chains propagating in [100]. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343860/ /pubmed/22589834 http://dx.doi.org/10.1107/S1600536812009919 Text en © Ejaz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ejaz, Khan, Islam Ullah Murtaza, Alina Harrison, William T. A. Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title | Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title_full | Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title_fullStr | Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title_full_unstemmed | Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title_short | Bis(methacrylato-κO)bis(2,4,6-trimethylpyridine-κN)copper(II) |
title_sort | bis(methacrylato-κo)bis(2,4,6-trimethylpyridine-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343860/ https://www.ncbi.nlm.nih.gov/pubmed/22589834 http://dx.doi.org/10.1107/S1600536812009919 |
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