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[meso-5,10,15,20-Tetrakis(5-bromothiophen-2-yl)porphyrinato-κ(4) N,N′,N′′,N′′′]nickel(II)
The Ni(II) atom in the title porphyrin complex, [Ni(C(36)H(16)Br(4)N(4)S(4))], is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N(4) donor set and the pyrrole rings being in the range 17.0 (3)–18...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343861/ https://www.ncbi.nlm.nih.gov/pubmed/22589835 http://dx.doi.org/10.1107/S1600536812011671 |