Bis[2-(diphenyl­phosphanyl-κP)benzaldehyde]­iodidogold(I)

In the title compound, [AuI(C(19)H(15)OP)(2)], the complete mol­ecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal–planar geometry within an IP(2) donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intra­molecular Au⋯O inter­...

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Detalles Bibliográficos
Autores principales: Williams, Michael L., Dunstan, Samuel P. C., Healy, Peter C., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343862/
https://www.ncbi.nlm.nih.gov/pubmed/22589836
http://dx.doi.org/10.1107/S1600536812011609
Descripción
Sumario:In the title compound, [AuI(C(19)H(15)OP)(2)], the complete mol­ecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal–planar geometry within an IP(2) donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intra­molecular Au⋯O inter­actions [3.172 (3) Å] are observed. No specific inter­molecular inter­actions are noted in the crystal packing.

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