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Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I)
In the title compound, [AuI(C(19)H(15)OP)(2)], the complete molecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal–planar geometry within an IP(2) donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intramolecular Au⋯O inter...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343862/ https://www.ncbi.nlm.nih.gov/pubmed/22589836 http://dx.doi.org/10.1107/S1600536812011609 |
| _version_ | 1782231862133915648 |
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| author | Williams, Michael L. Dunstan, Samuel P. C. Healy, Peter C. Tiekink, Edward R. T. |
| author_facet | Williams, Michael L. Dunstan, Samuel P. C. Healy, Peter C. Tiekink, Edward R. T. |
| author_sort | Williams, Michael L. |
| collection | PubMed |
| description | In the title compound, [AuI(C(19)H(15)OP)(2)], the complete molecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal–planar geometry within an IP(2) donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intramolecular Au⋯O interactions [3.172 (3) Å] are observed. No specific intermolecular interactions are noted in the crystal packing. |
| format | Online Article Text |
| id | pubmed-3343862 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438622012-05-15 Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) Williams, Michael L. Dunstan, Samuel P. C. Healy, Peter C. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AuI(C(19)H(15)OP)(2)], the complete molecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal–planar geometry within an IP(2) donor set with the greatest distortion seen in the P—Au—P angle [128.49 (3) °]. Close intramolecular Au⋯O interactions [3.172 (3) Å] are observed. No specific intermolecular interactions are noted in the crystal packing. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343862/ /pubmed/22589836 http://dx.doi.org/10.1107/S1600536812011609 Text en © Williams et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Williams, Michael L. Dunstan, Samuel P. C. Healy, Peter C. Tiekink, Edward R. T. Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title | Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title_full | Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title_fullStr | Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title_full_unstemmed | Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title_short | Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I) |
| title_sort | bis[2-(diphenylphosphanyl-κp)benzaldehyde]iodidogold(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343862/ https://www.ncbi.nlm.nih.gov/pubmed/22589836 http://dx.doi.org/10.1107/S1600536812011609 |
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