Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac

The title compound, [Cu(2)(C(14)H(10)Cl(2)NO(2))(4)(C(2)H(6)OS)(2)], comprises a Cu(II) (2) core that is quadruply bridged by four carboxyl­ate ligands with the dimethyl sulfoxide ligands binding along the Cu⋯Cu axis. The four carboxyl­ate ligands bind in a bidentate syn–syn bridging mode. Mol­ecule...

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Detalles Bibliográficos
Autores principales: Sayen, Stéphanie, Guillon, Emmanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343863/
https://www.ncbi.nlm.nih.gov/pubmed/22589837
http://dx.doi.org/10.1107/S160053681201152X
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author Sayen, Stéphanie
Guillon, Emmanuel
author_facet Sayen, Stéphanie
Guillon, Emmanuel
author_sort Sayen, Stéphanie
collection PubMed
description The title compound, [Cu(2)(C(14)H(10)Cl(2)NO(2))(4)(C(2)H(6)OS)(2)], comprises a Cu(II) (2) core that is quadruply bridged by four carboxyl­ate ligands with the dimethyl sulfoxide ligands binding along the Cu⋯Cu axis. The four carboxyl­ate ligands bind in a bidentate syn–syn bridging mode. Mol­ecules reside on crystallographic inversion centres bis­ecting the mid-point of the Cu⋯Cu axis. There are no inter­molecular inter­actions of note.
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spelling pubmed-33438632012-05-15 Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac Sayen, Stéphanie Guillon, Emmanuel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(14)H(10)Cl(2)NO(2))(4)(C(2)H(6)OS)(2)], comprises a Cu(II) (2) core that is quadruply bridged by four carboxyl­ate ligands with the dimethyl sulfoxide ligands binding along the Cu⋯Cu axis. The four carboxyl­ate ligands bind in a bidentate syn–syn bridging mode. Mol­ecules reside on crystallographic inversion centres bis­ecting the mid-point of the Cu⋯Cu axis. There are no inter­molecular inter­actions of note. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343863/ /pubmed/22589837 http://dx.doi.org/10.1107/S160053681201152X Text en © Sayen and Guillon 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sayen, Stéphanie
Guillon, Emmanuel
Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title_full Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title_fullStr Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title_full_unstemmed Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title_short Tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) O:O′}bis­[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear Cu(II) complex with the non-steroidal anti-inflammatory drug diclofenac
title_sort tetra­kis{2-[2-(2,6-dichloro­anilino)phen­yl]ethano­ato-κ(2) o:o′}bis­[(dimethyl sulfoxide-κo)copper(ii)](cu—cu): a binuclear cu(ii) complex with the non-steroidal anti-inflammatory drug diclofenac
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343863/
https://www.ncbi.nlm.nih.gov/pubmed/22589837
http://dx.doi.org/10.1107/S160053681201152X
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AT guillonemmanuel tetrakis2226dichloroanilinophenylethanoatok2oobisdimethylsulfoxidekocopperiicucuabinuclearcuiicomplexwiththenonsteroidalantiinflammatorydrugdiclofenac

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