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{2-[(2-Aminocyclohexyl)iminomethyl]phenolato}dioxidovanadium(V)
In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the ot...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343864/ https://www.ncbi.nlm.nih.gov/pubmed/22589838 http://dx.doi.org/10.1107/S1600536812011592 |
| Sumario: | In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, molecules are connected by N—H⋯O and N—H⋯(O,O) hydrogen bonds, forming a tetramer. |
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