{2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)

In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the ot...

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Autor principal: Sun, Xin-Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343864/
https://www.ncbi.nlm.nih.gov/pubmed/22589838
http://dx.doi.org/10.1107/S1600536812011592
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author Sun, Xin-Zhi
author_facet Sun, Xin-Zhi
author_sort Sun, Xin-Zhi
collection PubMed
description In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, mol­ecules are connected by N—H⋯O and N—H⋯(O,O) hydrogen bonds, forming a tetra­mer.
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spelling pubmed-33438642012-05-15 {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V) Sun, Xin-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, mol­ecules are connected by N—H⋯O and N—H⋯(O,O) hydrogen bonds, forming a tetra­mer. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343864/ /pubmed/22589838 http://dx.doi.org/10.1107/S1600536812011592 Text en © Xin-Zhi Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Xin-Zhi
{2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title_full {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title_fullStr {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title_full_unstemmed {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title_short {2-[(2-Amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(V)
title_sort {2-[(2-amino­cyclo­hex­yl)imino­meth­yl]phenolato}dioxidovanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343864/
https://www.ncbi.nlm.nih.gov/pubmed/22589838
http://dx.doi.org/10.1107/S1600536812011592
work_keys_str_mv AT sunxinzhi 22aminocyclohexyliminomethylphenolatodioxidovanadiumv

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