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(Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)

The Pt(II) ion in the title complex, [PtI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and by two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridin...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343866/
https://www.ncbi.nlm.nih.gov/pubmed/22589840
http://dx.doi.org/10.1107/S1600536812011907
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pt(II) ion in the title complex, [PtI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and by two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex mol­ecules are assembled through inter­molecular N—H⋯I hydrogen bonds, forming a dimer-type species. The complexes are stacked in columns along the b axis and display several inter­molecular π–π inter­actions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.997 (5) Å.
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spelling pubmed-33438662012-05-15 (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and by two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex mol­ecules are assembled through inter­molecular N—H⋯I hydrogen bonds, forming a dimer-type species. The complexes are stacked in columns along the b axis and display several inter­molecular π–π inter­actions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.997 (5) Å. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343866/ /pubmed/22589840 http://dx.doi.org/10.1107/S1600536812011907 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title_full (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title_fullStr (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title_full_unstemmed (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title_short (Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidoplatinum(II)
title_sort (di-2-pyridyl­amine-κ(2) n (2),n (2′))diiodidoplatinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343866/
https://www.ncbi.nlm.nih.gov/pubmed/22589840
http://dx.doi.org/10.1107/S1600536812011907
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