(Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)

In the title compound, [Rh(C(5)H(7)O(2))(C(18)H(14)BrP)(CO)], the Rh(I) atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetyl­acetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the...

Descripción completa

Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343868/
https://www.ncbi.nlm.nih.gov/pubmed/22589842
http://dx.doi.org/10.1107/S1600536812011944
_version_ 1782231863562076160
author Davis, Wade L.
Meijboom, Reinout
author_facet Davis, Wade L.
Meijboom, Reinout
author_sort Davis, Wade L.
collection PubMed
description In the title compound, [Rh(C(5)H(7)O(2))(C(18)H(14)BrP)(CO)], the Rh(I) atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetyl­acetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh(2)(2-BrC(6)H(4)) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data.
format Online
Article
Text
id pubmed-3343868
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33438682012-05-15 (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I) Davis, Wade L. Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(5)H(7)O(2))(C(18)H(14)BrP)(CO)], the Rh(I) atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh—O = 2.077 (2) and 2.033 (2) Å] of the acetyl­acetonate ligand, one carbonyl C atom [Rh—C = 1.813 (2) Å] and one P atom [Rh—P = 2.242 (5) Å] of the PPh(2)(2-BrC(6)H(4)) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.95:0.05 ratio. However, this disorder could not be resolved satisfactorily with the present data. International Union of Crystallography 2012-03-24 /pmc/articles/PMC3343868/ /pubmed/22589842 http://dx.doi.org/10.1107/S1600536812011944 Text en © Davis and Meijboom 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davis, Wade L.
Meijboom, Reinout
(Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title_full (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title_fullStr (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title_short (Acetyl­acetonato-κ(2) O,O′)[(2-bromo­phen­yl)diphenyl­phosphane-κP]carbonyl­rhodium(I)
title_sort (acetyl­acetonato-κ(2) o,o′)[(2-bromo­phen­yl)diphenyl­phosphane-κp]carbonyl­rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343868/
https://www.ncbi.nlm.nih.gov/pubmed/22589842
http://dx.doi.org/10.1107/S1600536812011944
work_keys_str_mv AT daviswadel acetylacetonatok2oo2bromophenyldiphenylphosphanekpcarbonylrhodiumi
AT meijboomreinout acetylacetonatok2oo2bromophenyldiphenylphosphanekpcarbonylrhodiumi

Ejemplares similares