Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate

In the title compound, [Rh(C(74)H(68)O(8)P(2))H(CO)(2)]·C(4)H(10)O, the C(2)HP(2) coordination set at the Rh(I) ion is arranged in a distorted trigonal–planar geometry with one P atom of the diphosphite mol­ecule and the H atom adopting the axial coordination sites.

Detalles Bibliográficos
Autores principales: Selent, Detlef, Spannenberg, Anke, Börner, Armin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343872/
https://www.ncbi.nlm.nih.gov/pubmed/22589846
http://dx.doi.org/10.1107/S1600536812011786
_version_ 1782231864515231744
author Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_facet Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_sort Selent, Detlef
collection PubMed
description In the title compound, [Rh(C(74)H(68)O(8)P(2))H(CO)(2)]·C(4)H(10)O, the C(2)HP(2) coordination set at the Rh(I) ion is arranged in a distorted trigonal–planar geometry with one P atom of the diphosphite mol­ecule and the H atom adopting the axial coordination sites.
format Online
Article
Text
id pubmed-3343872
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33438722012-05-15 Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate Selent, Detlef Spannenberg, Anke Börner, Armin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(74)H(68)O(8)P(2))H(CO)(2)]·C(4)H(10)O, the C(2)HP(2) coordination set at the Rh(I) ion is arranged in a distorted trigonal–planar geometry with one P atom of the diphosphite mol­ecule and the H atom adopting the axial coordination sites. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3343872/ /pubmed/22589846 http://dx.doi.org/10.1107/S1600536812011786 Text en © Selent et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Selent, Detlef
Spannenberg, Anke
Börner, Armin
Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title_full Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title_fullStr Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title_full_unstemmed Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title_short Dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κP]biphen­yl}hydridorhodium(I) diethyl ether monosolvate
title_sort dicarbonyl­{3,3′-di-tert-butyl-5,5′-di­meth­oxy-2,2′-bis­[(4,4,5,5-tetra­phenyl-1,3,2-dioxa­phospho­lan-2-yl)­oxy-κp]biphen­yl}hydridorhodium(i) diethyl ether monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343872/
https://www.ncbi.nlm.nih.gov/pubmed/22589846
http://dx.doi.org/10.1107/S1600536812011786
work_keys_str_mv AT selentdetlef dicarbonyl33ditertbutyl55dimethoxy22bis4455tetraphenyl132dioxaphospholan2yloxykpbiphenylhydridorhodiumidiethylethermonosolvate
AT spannenberganke dicarbonyl33ditertbutyl55dimethoxy22bis4455tetraphenyl132dioxaphospholan2yloxykpbiphenylhydridorhodiumidiethylethermonosolvate
AT bornerarmin dicarbonyl33ditertbutyl55dimethoxy22bis4455tetraphenyl132dioxaphospholan2yloxykpbiphenylhydridorhodiumidiethylethermonosolvate

Ejemplares similares