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cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate
In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343880/ https://www.ncbi.nlm.nih.gov/pubmed/22589848 http://dx.doi.org/10.1107/S1600536812012469 |
Sumario: | In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent molecule is linked to the metal complex by weak intermolecular C—H⋯O hydrogen bonds. |
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