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cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate

In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343880/
https://www.ncbi.nlm.nih.gov/pubmed/22589848
http://dx.doi.org/10.1107/S1600536812012469
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent mol­ecule is linked to the metal complex by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-33438802012-05-15 cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent mol­ecule is linked to the metal complex by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3343880/ /pubmed/22589848 http://dx.doi.org/10.1107/S1600536812012469 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title_full cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title_fullStr cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title_full_unstemmed cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title_short cis-Dichloridobis(quinoline-κN)­platinum(II) nitro­methane monosolvate
title_sort cis-dichloridobis(quinoline-κn)­platinum(ii) nitro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343880/
https://www.ncbi.nlm.nih.gov/pubmed/22589848
http://dx.doi.org/10.1107/S1600536812012469
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