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cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate
In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343880/ https://www.ncbi.nlm.nih.gov/pubmed/22589848 http://dx.doi.org/10.1107/S1600536812012469 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent molecule is linked to the metal complex by weak intermolecular C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3343880 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438802012-05-15 cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(−) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1 (1)°. The dihedral angle between the quinoline ligands is 88.3 (2)°. In the crystal, each solvent molecule is linked to the metal complex by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3343880/ /pubmed/22589848 http://dx.doi.org/10.1107/S1600536812012469 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title |
cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title_full |
cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title_fullStr |
cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title_full_unstemmed |
cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title_short |
cis-Dichloridobis(quinoline-κN)platinum(II) nitromethane monosolvate |
title_sort | cis-dichloridobis(quinoline-κn)platinum(ii) nitromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343880/ https://www.ncbi.nlm.nih.gov/pubmed/22589848 http://dx.doi.org/10.1107/S1600536812012469 |
work_keys_str_mv | AT hakwang cisdichloridobisquinolineknplatinumiinitromethanemonosolvate |