Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate

The Zn(II) atom in the title complex, [Zn(C(6)H(4)O(8)S(2))(H(2)O)(5)]·5H(2)O, is coordinated by five water mol­ecules and an O atom of a 4,6-dihy­droxy­benzene-1,3-disulfonate dianion. The coord­ination geometry is distorted octa­hedral, with the Zn—O(sulfonate) bond relatively long compared to the...

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Detalles Bibliográficos
Autores principales: Zhu, Zhi-Biao, Gao, Shan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343881/
https://www.ncbi.nlm.nih.gov/pubmed/22589849
http://dx.doi.org/10.1107/S1600536812012317
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author Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Zhu, Zhi-Biao
collection PubMed
description The Zn(II) atom in the title complex, [Zn(C(6)H(4)O(8)S(2))(H(2)O)(5)]·5H(2)O, is coordinated by five water mol­ecules and an O atom of a 4,6-dihy­droxy­benzene-1,3-disulfonate dianion. The coord­ination geometry is distorted octa­hedral, with the Zn—O(sulfonate) bond relatively long compared to the Zn—O(water) bonds. The coordinated and lattice water mol­ecules inter­act with each other and with the hy­droxy groups and sulfonate ligand through O—H⋯O hydrogen bonds, generating a tightly held three-dimensional network.
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spelling pubmed-33438812012-05-15 Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title complex, [Zn(C(6)H(4)O(8)S(2))(H(2)O)(5)]·5H(2)O, is coordinated by five water mol­ecules and an O atom of a 4,6-dihy­droxy­benzene-1,3-disulfonate dianion. The coord­ination geometry is distorted octa­hedral, with the Zn—O(sulfonate) bond relatively long compared to the Zn—O(water) bonds. The coordinated and lattice water mol­ecules inter­act with each other and with the hy­droxy groups and sulfonate ligand through O—H⋯O hydrogen bonds, generating a tightly held three-dimensional network. International Union of Crystallography 2012-03-28 /pmc/articles/PMC3343881/ /pubmed/22589849 http://dx.doi.org/10.1107/S1600536812012317 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R. T.
Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title_full Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title_fullStr Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title_full_unstemmed Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title_short Penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κO (1))zinc penta­hydrate
title_sort penta­aqua­(4,6-dihy­droxy­benzene-1,3-disulfonato-κo (1))zinc penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343881/
https://www.ncbi.nlm.nih.gov/pubmed/22589849
http://dx.doi.org/10.1107/S1600536812012317
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