catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]

In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Zn(H(2)O)(3) entities with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actio...

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Autores principales: Li, Ya-Feng, Gao, Yue, Xu, Yue, Qin, Xiao-Lin, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343885/
https://www.ncbi.nlm.nih.gov/pubmed/22589853
http://dx.doi.org/10.1107/S1600536812012111
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author Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
author_facet Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
author_sort Li, Ya-Feng
collection PubMed
description In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Zn(H(2)O)(3) entities with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Zn(H(2)O)(3)O(3) polyhedron displays a distorted octa­hedral geometry with one weak Zn—O(carboxyl­ate) coordination [2.433 (8) A°] and two water mol­ecules located in axial positions. Except for one of the axial water molecules and two adjacent H atoms, the other atoms (including H atoms) possess site symmetry m.
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spelling pubmed-33438852012-05-15 catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)] Li, Ya-Feng Gao, Yue Xu, Yue Qin, Xiao-Lin Gao, Wen-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(6)H(2)O(5))(H(2)O)(3)](n), an infinite chain is formed along [001] by linking of the Zn(H(2)O)(3) entities with one carboxyl­ate group of the furan-2,5-dicarboxyl­ate ligand. Adjacent chains are linked by O(water)—H⋯O hydrogen-bonding inter­actions. The Zn(H(2)O)(3)O(3) polyhedron displays a distorted octa­hedral geometry with one weak Zn—O(carboxyl­ate) coordination [2.433 (8) A°] and two water mol­ecules located in axial positions. Except for one of the axial water molecules and two adjacent H atoms, the other atoms (including H atoms) possess site symmetry m. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343885/ /pubmed/22589853 http://dx.doi.org/10.1107/S1600536812012111 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Feng
Gao, Yue
Xu, Yue
Qin, Xiao-Lin
Gao, Wen-Yuan
catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title_full catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title_fullStr catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title_full_unstemmed catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title_short catena-Poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) O (2):O (2),O (2′)]
title_sort catena-poly[(triaqua­zinc)-μ-furan-2,5-dicarboxyl­ato-κ(3) o (2):o (2),o (2′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343885/
https://www.ncbi.nlm.nih.gov/pubmed/22589853
http://dx.doi.org/10.1107/S1600536812012111
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