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Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate

The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-yl­amine (dpa) ligands. The Pd(I...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343886/
https://www.ncbi.nlm.nih.gov/pubmed/22589854
http://dx.doi.org/10.1107/S1600536812012081
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-yl­amine (dpa) ligands. The Pd(II) atom is located on an inversion centre, and thus the PdN(4) unit is exactly planar. The dpa ligand itself is not planar, showing a dihedral angle between the pyridine rings of 39.9 (1)°. The anions are connected to the complex by inter­molecular N—H⋯O hydrogen bonds between the two O atoms of the anion and the N—H group of the cation. Weak inter­molecular C—H⋯O hydrogen bonds additionally link the constituents in the crystal structure. The NO(3) (−) anion was found to be disordered over two sites with a site-occupancy factor of 0.55 (10) for the major component.
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spelling pubmed-33438862012-05-15 Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-yl­amine (dpa) ligands. The Pd(II) atom is located on an inversion centre, and thus the PdN(4) unit is exactly planar. The dpa ligand itself is not planar, showing a dihedral angle between the pyridine rings of 39.9 (1)°. The anions are connected to the complex by inter­molecular N—H⋯O hydrogen bonds between the two O atoms of the anion and the N—H group of the cation. Weak inter­molecular C—H⋯O hydrogen bonds additionally link the constituents in the crystal structure. The NO(3) (−) anion was found to be disordered over two sites with a site-occupancy factor of 0.55 (10) for the major component. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343886/ /pubmed/22589854 http://dx.doi.org/10.1107/S1600536812012081 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title_full Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title_fullStr Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title_full_unstemmed Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title_short Bis(dipyridin-2-yl­amine-κ(2) N (2),N (2′))palladium(II) dinitrate
title_sort bis(dipyridin-2-yl­amine-κ(2) n (2),n (2′))palladium(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343886/
https://www.ncbi.nlm.nih.gov/pubmed/22589854
http://dx.doi.org/10.1107/S1600536812012081
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