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Bis(dipyridin-2-ylamine-κ(2) N (2),N (2′))palladium(II) dinitrate
The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-ylamine (dpa) ligands. The Pd(I...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343886/ https://www.ncbi.nlm.nih.gov/pubmed/22589854 http://dx.doi.org/10.1107/S1600536812012081 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-ylamine (dpa) ligands. The Pd(II) atom is located on an inversion centre, and thus the PdN(4) unit is exactly planar. The dpa ligand itself is not planar, showing a dihedral angle between the pyridine rings of 39.9 (1)°. The anions are connected to the complex by intermolecular N—H⋯O hydrogen bonds between the two O atoms of the anion and the N—H group of the cation. Weak intermolecular C—H⋯O hydrogen bonds additionally link the constituents in the crystal structure. The NO(3) (−) anion was found to be disordered over two sites with a site-occupancy factor of 0.55 (10) for the major component. |
format | Online Article Text |
id | pubmed-3343886 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438862012-05-15 Bis(dipyridin-2-ylamine-κ(2) N (2),N (2′))palladium(II) dinitrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pd(C(10)H(9)N(3))(2)](NO(3))(2), contains one half of a cationic Pd(II) complex and one NO(3) (−) anion. In the complex, the Pd(II) ion is four-coordinated by four pyridine N atoms derived from the two chelating dipyridin-2-ylamine (dpa) ligands. The Pd(II) atom is located on an inversion centre, and thus the PdN(4) unit is exactly planar. The dpa ligand itself is not planar, showing a dihedral angle between the pyridine rings of 39.9 (1)°. The anions are connected to the complex by intermolecular N—H⋯O hydrogen bonds between the two O atoms of the anion and the N—H group of the cation. Weak intermolecular C—H⋯O hydrogen bonds additionally link the constituents in the crystal structure. The NO(3) (−) anion was found to be disordered over two sites with a site-occupancy factor of 0.55 (10) for the major component. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343886/ /pubmed/22589854 http://dx.doi.org/10.1107/S1600536812012081 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Bis(dipyridin-2-ylamine-κ(2) N (2),N (2′))palladium(II) dinitrate |
title | Bis(dipyridin-2-ylamine-κ(2)
N
(2),N
(2′))palladium(II) dinitrate |
title_full | Bis(dipyridin-2-ylamine-κ(2)
N
(2),N
(2′))palladium(II) dinitrate |
title_fullStr | Bis(dipyridin-2-ylamine-κ(2)
N
(2),N
(2′))palladium(II) dinitrate |
title_full_unstemmed | Bis(dipyridin-2-ylamine-κ(2)
N
(2),N
(2′))palladium(II) dinitrate |
title_short | Bis(dipyridin-2-ylamine-κ(2)
N
(2),N
(2′))palladium(II) dinitrate |
title_sort | bis(dipyridin-2-ylamine-κ(2)
n
(2),n
(2′))palladium(ii) dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343886/ https://www.ncbi.nlm.nih.gov/pubmed/22589854 http://dx.doi.org/10.1107/S1600536812012081 |
work_keys_str_mv | AT hakwang bisdipyridin2ylaminek2n2n2palladiumiidinitrate |