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Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)

In the title complex, [Pd(CH(3)COO)(2)(C(10)H(9)N(3))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two O atoms from two anionic acetate ligands. The dpa ligand coordinates the Pd(II...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343887/
https://www.ncbi.nlm.nih.gov/pubmed/22589855
http://dx.doi.org/10.1107/S1600536812012093
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [Pd(CH(3)COO)(2)(C(10)H(9)N(3))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two O atoms from two anionic acetate ligands. The dpa ligand coordinates the Pd(II) atom in a boat conformation of the resulting chelate ring; the dihedral angle between the pyridine rings is 39.3 (2)°. The two acetate anions coordinate the Pd(II) atom as monodentate ligands and are located on the same sides of the PdN(2)O(2) unit plane. The carboxyl­ate groups of the anionic ligands appear to be delocalized on the basis of the C—O bond lengths. Two complex mol­ecules are assembled through inter­molecular N—H⋯O hydrogen bonds, forming a dimer-type species. Inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal structure.
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spelling pubmed-33438872012-05-15 Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(CH(3)COO)(2)(C(10)H(9)N(3))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two O atoms from two anionic acetate ligands. The dpa ligand coordinates the Pd(II) atom in a boat conformation of the resulting chelate ring; the dihedral angle between the pyridine rings is 39.3 (2)°. The two acetate anions coordinate the Pd(II) atom as monodentate ligands and are located on the same sides of the PdN(2)O(2) unit plane. The carboxyl­ate groups of the anionic ligands appear to be delocalized on the basis of the C—O bond lengths. Two complex mol­ecules are assembled through inter­molecular N—H⋯O hydrogen bonds, forming a dimer-type species. Inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal structure. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343887/ /pubmed/22589855 http://dx.doi.org/10.1107/S1600536812012093 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_full Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_fullStr Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_full_unstemmed Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_short Bis(acetato-κO)(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II)
title_sort bis(acetato-κo)(di-2-pyridyl­amine-κ(2) n (2),n (2′))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343887/
https://www.ncbi.nlm.nih.gov/pubmed/22589855
http://dx.doi.org/10.1107/S1600536812012093
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