Di-μ-methano­lato-κ(4) O:O-bis­[bis­(3-methyl-5-phenyl-1H-pyrazole-κN (2))(nitrato-κO)copper(II)]

Copper nitrate in methanol solution cleaves the N—C(methanol) bond when reacted with 3-methyl-5-phenyl­pyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methano­late ion...

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Detalles Bibliográficos
Autores principales: Li, Xu-Guang, Gao, Meng-Meng, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343888/
https://www.ncbi.nlm.nih.gov/pubmed/22589856
http://dx.doi.org/10.1107/S160053681201241X
Descripción
Sumario:Copper nitrate in methanol solution cleaves the N—C(methanol) bond when reacted with 3-methyl-5-phenyl­pyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methano­late ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intra­molecular N—H⋯O hydrogen bonds.

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