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Di-μ-methanolato-κ(4) O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN (2))(nitrato-κO)copper(II)]
Copper nitrate in methanol solution cleaves the N—C(methanol) bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methanolate ion...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343888/ https://www.ncbi.nlm.nih.gov/pubmed/22589856 http://dx.doi.org/10.1107/S160053681201241X |
| _version_ | 1782231867360018432 |
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| author | Li, Xu-Guang Gao, Meng-Meng Ng, Seik Weng |
| author_facet | Li, Xu-Guang Gao, Meng-Meng Ng, Seik Weng |
| author_sort | Li, Xu-Guang |
| collection | PubMed |
| description | Copper nitrate in methanol solution cleaves the N—C(methanol) bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3343888 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438882012-05-15 Di-μ-methanolato-κ(4) O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN (2))(nitrato-κO)copper(II)] Li, Xu-Guang Gao, Meng-Meng Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Copper nitrate in methanol solution cleaves the N—C(methanol) bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343888/ /pubmed/22589856 http://dx.doi.org/10.1107/S160053681201241X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xu-Guang Gao, Meng-Meng Ng, Seik Weng Di-μ-methanolato-κ(4) O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN (2))(nitrato-κO)copper(II)] |
| title | Di-μ-methanolato-κ(4)
O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN
(2))(nitrato-κO)copper(II)] |
| title_full | Di-μ-methanolato-κ(4)
O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN
(2))(nitrato-κO)copper(II)] |
| title_fullStr | Di-μ-methanolato-κ(4)
O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN
(2))(nitrato-κO)copper(II)] |
| title_full_unstemmed | Di-μ-methanolato-κ(4)
O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN
(2))(nitrato-κO)copper(II)] |
| title_short | Di-μ-methanolato-κ(4)
O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN
(2))(nitrato-κO)copper(II)] |
| title_sort | di-μ-methanolato-κ(4)
o:o-bis[bis(3-methyl-5-phenyl-1h-pyrazole-κn
(2))(nitrato-κo)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343888/ https://www.ncbi.nlm.nih.gov/pubmed/22589856 http://dx.doi.org/10.1107/S160053681201241X |
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