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Bis(2-{[(9H-fluoren-2-yl)methyl­idene]amino}­phenolato-κ(2) N,O)zinc methanol disolvate

In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methyl­idene]amino}­phenolate ligands within a distorted tetra­hedral geometry. The dihedr...

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Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Yun, Sung-Jae, Hwang, Inn-Hye, Kim, Dae-Young, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343889/
https://www.ncbi.nlm.nih.gov/pubmed/22589857
http://dx.doi.org/10.1107/S160053681201272X
Descripción
Sumario:In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methyl­idene]amino}­phenolate ligands within a distorted tetra­hedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O—H⋯O hydrogen bonds link the complex mol­ecules to the methanol solvent mol­ecules.