Cargando…
Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2) N,O)zinc methanol disolvate
In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methylidene]amino}phenolate ligands within a distorted tetrahedral geometry. The dihedr...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343889/ https://www.ncbi.nlm.nih.gov/pubmed/22589857 http://dx.doi.org/10.1107/S160053681201272X |
| _version_ | 1782231867584413696 |
|---|---|
| author | Kim, Young-Inn Yun, Sung-Jae Hwang, Inn-Hye Kim, Dae-Young Kang, Sung Kwon |
| author_facet | Kim, Young-Inn Yun, Sung-Jae Hwang, Inn-Hye Kim, Dae-Young Kang, Sung Kwon |
| author_sort | Kim, Young-Inn |
| collection | PubMed |
| description | In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methylidene]amino}phenolate ligands within a distorted tetrahedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O—H⋯O hydrogen bonds link the complex molecules to the methanol solvent molecules. |
| format | Online Article Text |
| id | pubmed-3343889 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33438892012-05-15 Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2) N,O)zinc methanol disolvate Kim, Young-Inn Yun, Sung-Jae Hwang, Inn-Hye Kim, Dae-Young Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(20)H(14)NO)(2)]·2CH(3)OH, the Zn(II) atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methylidene]amino}phenolate ligands within a distorted tetrahedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O—H⋯O hydrogen bonds link the complex molecules to the methanol solvent molecules. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343889/ /pubmed/22589857 http://dx.doi.org/10.1107/S160053681201272X Text en © Kim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kim, Young-Inn Yun, Sung-Jae Hwang, Inn-Hye Kim, Dae-Young Kang, Sung Kwon Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2) N,O)zinc methanol disolvate |
| title | Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
N,O)zinc methanol disolvate |
| title_full | Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
N,O)zinc methanol disolvate |
| title_fullStr | Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
N,O)zinc methanol disolvate |
| title_full_unstemmed | Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
N,O)zinc methanol disolvate |
| title_short | Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
N,O)zinc methanol disolvate |
| title_sort | bis(2-{[(9h-fluoren-2-yl)methylidene]amino}phenolato-κ(2)
n,o)zinc methanol disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343889/ https://www.ncbi.nlm.nih.gov/pubmed/22589857 http://dx.doi.org/10.1107/S160053681201272X |
| work_keys_str_mv | AT kimyounginn bis29hfluoren2ylmethylideneaminophenolatok2nozincmethanoldisolvate AT yunsungjae bis29hfluoren2ylmethylideneaminophenolatok2nozincmethanoldisolvate AT hwanginnhye bis29hfluoren2ylmethylideneaminophenolatok2nozincmethanoldisolvate AT kimdaeyoung bis29hfluoren2ylmethylideneaminophenolatok2nozincmethanoldisolvate AT kangsungkwon bis29hfluoren2ylmethylideneaminophenolatok2nozincmethanoldisolvate |