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Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)

The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex mol­ecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octa­hedral CoN(2)O(4) geometry. The Co(II...

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Autores principales: Wang, Kun-Miao, Zhou, Jie, Qian, Fen-Hua, Liu, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343890/
https://www.ncbi.nlm.nih.gov/pubmed/22589858
http://dx.doi.org/10.1107/S1600536812012251
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author Wang, Kun-Miao
Zhou, Jie
Qian, Fen-Hua
Liu, Jing
author_facet Wang, Kun-Miao
Zhou, Jie
Qian, Fen-Hua
Liu, Jing
author_sort Wang, Kun-Miao
collection PubMed
description The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex mol­ecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octa­hedral CoN(2)O(4) geometry. The Co(II) ion is coordinated by the pyridine N atoms from NITpPy ligands [NITpPy is 4,4,5,5-tetra­methyl-2-(pyridin-4-yl)imidazoline-1-oxyl 3-oxide), water O atoms and two monodentate benzoate O atoms. The complex mol­ecules are connected by O—H⋯O hydrogen bonds between water mol­ecules and benzoate ligands, forming chains parallel to [100]. π–π stacking inter­actions between the benzoate ligands with centroid–centroid distances of 3.752 (2) Å connect the chains into layers parallel to (10-1).
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spelling pubmed-33438902012-05-15 Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) Wang, Kun-Miao Zhou, Jie Qian, Fen-Hua Liu, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex mol­ecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octa­hedral CoN(2)O(4) geometry. The Co(II) ion is coordinated by the pyridine N atoms from NITpPy ligands [NITpPy is 4,4,5,5-tetra­methyl-2-(pyridin-4-yl)imidazoline-1-oxyl 3-oxide), water O atoms and two monodentate benzoate O atoms. The complex mol­ecules are connected by O—H⋯O hydrogen bonds between water mol­ecules and benzoate ligands, forming chains parallel to [100]. π–π stacking inter­actions between the benzoate ligands with centroid–centroid distances of 3.752 (2) Å connect the chains into layers parallel to (10-1). International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343890/ /pubmed/22589858 http://dx.doi.org/10.1107/S1600536812012251 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Kun-Miao
Zhou, Jie
Qian, Fen-Hua
Liu, Jing
Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title_full Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title_fullStr Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title_full_unstemmed Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title_short Diaqua­bis­(benzoato-κO)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
title_sort diaqua­bis­(benzoato-κo)bis­[4,4,5,5-tetra­methyl-2-(pyridin-4-yl-κn)imidazoline-1-oxyl 3-oxide]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343890/
https://www.ncbi.nlm.nih.gov/pubmed/22589858
http://dx.doi.org/10.1107/S1600536812012251
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