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Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II)
The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex molecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octahedral CoN(2)O(4) geometry. The Co(II...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343890/ https://www.ncbi.nlm.nih.gov/pubmed/22589858 http://dx.doi.org/10.1107/S1600536812012251 |
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author | Wang, Kun-Miao Zhou, Jie Qian, Fen-Hua Liu, Jing |
author_facet | Wang, Kun-Miao Zhou, Jie Qian, Fen-Hua Liu, Jing |
author_sort | Wang, Kun-Miao |
collection | PubMed |
description | The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex molecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octahedral CoN(2)O(4) geometry. The Co(II) ion is coordinated by the pyridine N atoms from NITpPy ligands [NITpPy is 4,4,5,5-tetramethyl-2-(pyridin-4-yl)imidazoline-1-oxyl 3-oxide), water O atoms and two monodentate benzoate O atoms. The complex molecules are connected by O—H⋯O hydrogen bonds between water molecules and benzoate ligands, forming chains parallel to [100]. π–π stacking interactions between the benzoate ligands with centroid–centroid distances of 3.752 (2) Å connect the chains into layers parallel to (10-1). |
format | Online Article Text |
id | pubmed-3343890 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438902012-05-15 Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) Wang, Kun-Miao Zhou, Jie Qian, Fen-Hua Liu, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(7)H(5)O(2))(2)(C(12)H(16)N(3)O(2))(2)(H(2)O)(2)], was obtained from a conventional solvent evaporation method. The complex molecule is centrosymmetric, so pairs of equivalent ligands lie trans to each other in a slightly distorted octahedral CoN(2)O(4) geometry. The Co(II) ion is coordinated by the pyridine N atoms from NITpPy ligands [NITpPy is 4,4,5,5-tetramethyl-2-(pyridin-4-yl)imidazoline-1-oxyl 3-oxide), water O atoms and two monodentate benzoate O atoms. The complex molecules are connected by O—H⋯O hydrogen bonds between water molecules and benzoate ligands, forming chains parallel to [100]. π–π stacking interactions between the benzoate ligands with centroid–centroid distances of 3.752 (2) Å connect the chains into layers parallel to (10-1). International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343890/ /pubmed/22589858 http://dx.doi.org/10.1107/S1600536812012251 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Kun-Miao Zhou, Jie Qian, Fen-Hua Liu, Jing Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title | Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title_full | Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title_fullStr | Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title_full_unstemmed | Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title_short | Diaquabis(benzoato-κO)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κN)imidazoline-1-oxyl 3-oxide]cobalt(II) |
title_sort | diaquabis(benzoato-κo)bis[4,4,5,5-tetramethyl-2-(pyridin-4-yl-κn)imidazoline-1-oxyl 3-oxide]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343890/ https://www.ncbi.nlm.nih.gov/pubmed/22589858 http://dx.doi.org/10.1107/S1600536812012251 |
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