trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate

The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Meyer-Wegner, Frank, Lerner, Hans-Wolfram, Sinke, Tanja, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343891/
https://www.ncbi.nlm.nih.gov/pubmed/22589859
http://dx.doi.org/10.1107/S1600536812012494
Descripción
Sumario:The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl­phosphane)­palladium(II) 1,4-dichloro­benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015–1017].

Ejemplares similares