trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate

The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The...

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Autores principales: Meyer-Wegner, Frank, Lerner, Hans-Wolfram, Sinke, Tanja, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343891/
https://www.ncbi.nlm.nih.gov/pubmed/22589859
http://dx.doi.org/10.1107/S1600536812012494
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author Meyer-Wegner, Frank
Lerner, Hans-Wolfram
Sinke, Tanja
Bolte, Michael
author_facet Meyer-Wegner, Frank
Lerner, Hans-Wolfram
Sinke, Tanja
Bolte, Michael
author_sort Meyer-Wegner, Frank
collection PubMed
description The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl­phosphane)­palladium(II) 1,4-dichloro­benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015–1017].
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spelling pubmed-33438912012-05-15 trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate Meyer-Wegner, Frank Lerner, Hans-Wolfram Sinke, Tanja Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol­ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl­phosphane)­palladium(II) 1,4-dichloro­benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015–1017]. International Union of Crystallography 2012-03-31 /pmc/articles/PMC3343891/ /pubmed/22589859 http://dx.doi.org/10.1107/S1600536812012494 Text en © Meyer-Wegner et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meyer-Wegner, Frank
Lerner, Hans-Wolfram
Sinke, Tanja
Bolte, Michael
trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title_full trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title_fullStr trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title_full_unstemmed trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title_short trans-Dichloridobis(triphenyl­phosphane-κP)palladium(II) benzene hemisolvate
title_sort trans-dichloridobis(triphenyl­phosphane-κp)palladium(ii) benzene hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343891/
https://www.ncbi.nlm.nih.gov/pubmed/22589859
http://dx.doi.org/10.1107/S1600536812012494
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AT sinketanja transdichloridobistriphenylphosphanekppalladiumiibenzenehemisolvate
AT boltemichael transdichloridobistriphenylphosphanekppalladiumiibenzenehemisolvate

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